Zinc(II) and nickel(II) complexes with N-[2-(2-diethylphoshponylethyliminomethyl) phenyl]-4-methylbenzenesulfonamide: Synthesis, structure, and photoluminescence properties

被引：0

作者：

Burlov, Anatolii S. ^{[1
]}

Vlasenko, Valery G. ^{[2
]}

Popov, Leonid D. ^{[3
]}

Koshchienko, Yurii, V ^{[1
]}

Garnovskii, Dmitrii A. ^{[4
]}

Kolodina, Alexandra A. ^{[1
]}

Korshunova, Evgeniya, V ^{[1
]}

Zubavichus, Yan, V ^{[5
]}

Lazarenko, Vladimir A. ^{[6
]}

机构：

[1] Southern Fed Univ, Inst Phys & Organ Chem, Stachki Ave 194-2, Rostov Na Donu 344090, Russia

[2] Southern Fed Univ, Inst Phys, Stachki Ave 194, Rostov Na Donu 344090, Russia

[3] Southern Fed Univ, Dept Chem, Zorge St 7, Rostov Na Donu 344090, Russia

[4] Russian Acad Sci, Southern Sci Ctr, 41 Chekhova Str, Rostov Na Donu 344006, Russia

[5] Russian Acad Sci, Boreskov Inst Catalysis, Synchrotron Radiat Facil SKIF, Siberian Branch, Nikolskii Pr 1, Koltsov 630559, Russia

[6] Natl Res Ctr, Kurchatov Inst, Acad Kurchatov Sq 1, Moscow 123182, Russia

来源：

INORGANICA CHIMICA ACTA | 2023年 / 558卷

关键词：

Federation; Azomethines; Zinc and nickel complexes; UV -Vis spectra; Photoluminescence; Synchrotron single -crystal X-ray diffraction; SCHIFF-BASE; ELECTROLUMINESCENT PROPERTIES; ELECTROCHEMICAL SYNTHESIS; LUMINESCENT PROPERTIES; CRYSTAL-STRUCTURES; METAL-COMPLEXES; PYRAZOLE; LIGAND; OXIDATION; NI(II);

D O I：

10.1016/j.ica.2023.121765

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two Zn(II) and Ni(II) complexes derived from the N-[2-(2-diethylphosphonylethyliminomethyl)phenyl]-4methylbenzenesulfonamide ligand (HL) with stoichiometry ML2 (M = Zn, Ni) have been synthesized. Their structures have been established using elemental analysis, IR, 1H NMR, UV-Vis spectroscopy, and synchrotron single-crystal X-ray diffraction. The Zn(II) and Ni(II) metal sites therein adopt the tetrahedral configuration. The DMSO and toluene solutions of the Zn(II) complex manifest photoluminescence in the blue-violet spectral range characterized by PL maxima at 436 and 432 nm and quantum yields of 0.15 and 0.30, respectively.

引用

页数：10

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