Strategies for Achieving Oxygen Tolerance in Reversible Addition-Fragmentation Chain Transfer Polymerization

被引：22

作者：

Ng, Gervase ^{[1
,2
]}

Prescott, Stuart W. W. ^{[1
,2
]}

Postma, Almar ^{[3
]}

Moad, Graeme ^{[3
]}

Hawker, Craig J. J. ^{[4
,5
,6
]}

Boyer, Cyrille ^{[1
,2
]}

机构：

[1] Univ New South Wales, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

[2] Univ New South Wales, Australian Ctr Nanomed, Sch Chem Engn, Sydney, NSW 2052, Australia

[3] CSIRO Mfg, Bag 10, Clayton, Vic 3169, Australia

[4] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[5] Univ Calif Santa Barbara, Dept Mat Chem, Santa Barbara, CA 93106 USA

[6] Univ Calif Santa Barbara, Dept Biochem, Santa Barbara, CA 93106 USA

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2023年 / 224卷 / 19期

基金：

澳大利亚研究理事会;

关键词：

controlled; living radical polymerization; oxygen tolerance; RAFT polymerization; LIVING RADICAL POLYMERIZATION; PET-RAFT POLYMERIZATION; ROOM-TEMPERATURE RAFT; MULTIBLOCK COPOLYMERS; DIFFUSION-COEFFICIENTS; COMBINATORIAL APPROACH; ORGANIC-SOLVENTS; GLUCOSE-OXIDASE; SURFACE; MECHANISM;

D O I：

10.1002/macp.202300132

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Reversible addition-fragmentation chain transfer polymerization (RAFT) is a popular method for the synthesis of well-defined macromolecules, but its sensitivity to oxygen is a major limitation for many industrial applications. Recent research has focused on developing strategies to confer oxygen tolerance onto RAFT polymerization, eliminating the need for deoxygenation steps and allowing for simpler reaction conditions. This minireview highlights several promising approaches to achieve oxygen tolerance in RAFT polymerization, including enzyme-mediated, alkylborane-initiated, and photomediated methods. The potential applications of oxygen-tolerant RAFT polymerization are also discussed, demonstrating the promise for significant advances in large-scale industrial polymer synthesis.

引用

页数：23

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