Significantly enhanced activation of peroxymonosulfate by a graphene-supported BiFeO3 composites for highly efficient degradation of tetracycline hydrochloride

被引:3
作者
Ma, Jingwen [1 ]
Xing, Hongjie [1 ]
Zhang, Jingji [1 ]
Zong, Quan [1 ]
Du, Huiwei [1 ]
Chen, Junfu [1 ]
Wang, Jiangying [1 ]
机构
[1] China Jiliang Univ, Coll Mat & Chem, Hangzhou 310018, Peoples R China
关键词
Graphene; Ultrasound assisted activation; Tetracycline; Peroxymonosulfate; BiFeO3; VISIBLE-LIGHT; OXIDE; OXIDATION; PHOTOCATALYSIS; PHARMACEUTICALS; NANOCOMPOSITE; ADSORPTION; REMOVAL; WATER;
D O I
10.1016/j.solidstatesciences.2023.107163
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
To enhance active site of BiFeO3, graphene is employed to support BiFeO3 for promoting degradation of tetracycline. Herein, graphene-supported BiFeO3 composites are prepared via a facile two-step hydrothermal process and their ultrasound assisted activation of peroxymonosulfate is investigated. Benefiting from graphene loading, the specific surface area of composite with 2% graphene is about twice that of pure BiFeO3, leading to a high Fe2+ level. The high Fe2+ level promotes ultrasound assisted activation of peroxymonosulfate for effectively degrading tetracycline hydrochloride. In particular, the removal rate reaches up to similar to 100% after 6 min reaction under 50 W ultrasonic radiation. The composite catalyst is stable and recyclable, which can be applied in practical wastewater treatment.
引用
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页数:6
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共 55 条
[1]   Kinetics of aqueous chlorination of some pharmaceuticals and their elimination from water matrices [J].
Acero, Juan L. ;
Javier Benitez, F. ;
Real, Francisco J. ;
Roldan, Gloria .
WATER RESEARCH, 2010, 44 (14) :4158-4170
[2]   Molecular Design for Tailoring a Single-Source Precursor for Bismuth Ferrite [J].
Bendt, Georg ;
Schiwon, Rafael ;
Salamon, Soma ;
Landers, Joachim ;
Hagemann, Ulrich ;
Limberg, Christian ;
Wende, Heiko ;
Schulz, Stephan .
INORGANIC CHEMISTRY, 2016, 55 (15) :7542-7549
[3]   Interfacial engineering in 3D/2D and 1D/2D bismuth ferrite (BiFeO3)/Graphene oxide nanocomposites for the enhanced photocatalytic activities under sunlight [J].
Bharathkumar, S. ;
Sakar, M. ;
Archana, J. ;
Navaneethan, M. ;
Balakumar, S. .
CHEMOSPHERE, 2021, 284
[4]   Dual oxidation state induced oxygen vacancies in Pr substituted BiFeO3 compounds: An effective material activation strategy to enhance the magnetic and visible light-driven photocatalytic properties [J].
Bharathkumar, S. ;
Sakar, M. ;
Ponpandian, N. ;
Balakumar, S. .
MATERIALS RESEARCH BULLETIN, 2018, 101 :107-115
[5]   Covalently functionalized graphene by thiourea for enhancing H2-evolution performance of TiO2 photocatalyst [J].
Cao, Yanjie ;
Wang, Ping ;
Fan, Jiajie ;
Yu, Huogen .
CERAMICS INTERNATIONAL, 2021, 47 (01) :654-661
[6]   Controlling hydroxyl content of reduced graphene oxide for superior cathode performance of lithium sulfur batteries [J].
Chen, Liping ;
Yang, Rong ;
Yan, Yinling ;
Zou, Yiming ;
Li, Xifei ;
Deng, Qijiu ;
Xu, Yunhua .
ELECTROCHIMICA ACTA, 2020, 362
[7]   Graphitic carbon nitride/SmFeO3composite Z-scheme photocatalyst with high visible light activity [J].
Chouchene, Bilel ;
Gries, Thomas ;
Balan, Lavinia ;
Medjahdi, Ghouti ;
Schneider, Raphael .
NANOTECHNOLOGY, 2020, 31 (46)
[8]   Hollow bismuth ferrite combined graphene as advanced anode material for sodium-ion batteries [J].
Ding, Xuli ;
Liu, Yi .
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2020, 30 (02) :153-159
[9]   Oxalic acid functionalization of BaTiO3 nanobelts for promoting their piezo-degradation organic contaminants [J].
Gao, Shitao ;
Xing, Hongjie ;
Zhang, Jingji ;
Liu, Yapi ;
Du, Huiwei ;
Zhu, Zejie ;
Wang, Jiangying ;
Li, Xu ;
Zhang, Suwei ;
Yao, Yaxuan ;
Ren, Lingling .
JOURNAL OF MATERIOMICS, 2021, 7 (06) :1275-1283
[10]   Degradation of antibiotic pollutants by persulfate activated with various carbon materials [J].
Gao, Yuan ;
Wang, Qing ;
Ji, Guozhao ;
Li, Aimin .
CHEMICAL ENGINEERING JOURNAL, 2022, 429