Heterogeneous single-atom catalysts for energy process: recent progress, applications and challenges

被引：19

作者：

Gong, Xue ^{[1
]}

Song, Ping ^{[1
]}

Han, Ce ^{[1
]}

Xiao, Yi ^{[2
]}

Mei, Xuanhao ^{[1
,3
]}

Xu, Weilin ^{[1
,3
,4
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Jilin Prov Key Lab Low Carbon Chem Power, Changchun 130022, Jilin, Peoples R China

[2] Nanyang Technol Univ, Inst Digital Mol Analyt & Sci, Singapore 637457, Singapore

[3] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China

[4] Chinese Acad Sci, State Key Lab Electroanalyt Chem, Changchun Inst Appl Chem, Jilin Prov Key Lab Low Carbon Chem Power, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China

来源：

ENERGY MATERIALS | 2023年 / 3卷 / 02期

基金：

国家重点研发计划; 美国国家科学基金会; 中国国家自然科学基金;

关键词：

Single-atom catalysts; synthesis method; substrates; structure and properties; applications; OXYGEN REDUCTION REACTION; NITROGEN-DOPED GRAPHENE; EFFICIENT HYDROGEN EVOLUTION; METAL-ORGANIC FRAMEWORKS; WATER-GAS SHIFT; CO2; REDUCTION; ACTIVE-SITES; HIGHLY EFFICIENT; METHANE CONVERSION; TITANIUM-DIOXIDE;

D O I：

10.20517/energymater.2022.82

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Single-atom catalysts (SACs) with high activity, unique selectivity, and nearly 100% atom utilization efficiency are promising for broad applications in many fields. This review aims to provide a summary of the current development of SACs and point out their challenges and opportunities for commercial applications in the energy process. The discussion starts with an introduction of various types of SACs materials, followed by typical SACs synthetic methods with concrete examples and commonly used characterization methods. The state-of-the-art synthesis methods, whereby SACs with stabilized single metal atoms on the substrate without migration and agglomeration could be obtained, are emphasized. Next, we give an overview of different types of substrates and discuss the effects of substrate species on the structure and properties of SACs. Then we highlight the typical applications of SACs and the remaining challenges. Finally, a perspective on the opportunities for the development of SACs for future commercial applications is provided.

引用

页数：28

共 162 条

[31] Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes [J].