N/S co-doped carbon nanosheets derived from sugarcane processing by-products for flexible solid-state supercapacitors

被引:14
作者
Shi, Fangfang [1 ]
Zhang, Zhengchu [1 ]
Xu, Yongjie [1 ]
Yang, Chao [1 ]
Qiu, Jianhui [2 ]
Liao, Jiachi [3 ]
Zang, Limin [1 ]
机构
[1] Guilin Univ Technol, Guangxi Coll & Univ Key Lab Nat & Biomed Polymer M, Coll Mat Sci & Engn, Guilin 541004, Peoples R China
[2] Akita Prefectural Univ, Fac Syst Sci & Technol, Dept Machine Intelligence & Syst Engn, Yurihonjo 0150055, Japan
[3] Northwestern Polytech Univ, Queen Mary Univ London, Engn Sch, Xian 710072, Peoples R China
基金
中国国家自然科学基金;
关键词
Supercapacitor; Carbonization; Biomass -derived carbon; Sulfonated potassium fulvic acid; ANODE MATERIAL; NITROGEN; GRAPHENE; CARBONIZATION; COMPOSITES; OXIDE;
D O I
10.1016/j.jelechem.2023.117217
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Developing sustainable carbon materials from biomass for supercapacitors is a promising solution to alleviate energy and environmental pressures. In this paper, novel N/S co-doped carbon nanosheets derived from sug-arcane processing by-products are proposed. Flexible and binder-free electrodes based on carbon felt and sul-fonated potassium fulvic acid were prepared by a simple impregnation-carbonization method. The maximum areal specific capacitance, power density and energy density of the symmetric supercapacitor are 409.9 mF cm-2 (1 mA cm-2), 0.92 mW cm-2 and 184.5 mu Wh cm-2, respectively. The operating voltage of the device increases to 1.8 V by using LiCl electrolyte. After 10,000 cycles, the capacitance remains 90 % of its initial value. Besides, the device possesses good flexibility, which can be bent at different angles and has a capacitance retention of 92.3 % after 5000 bending cycles. The supercapacitor is of great significance for the recovery of crop processing by-products to prepare flexible electronic devices.
引用
收藏
页数:9
相关论文
共 48 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Nitrogen and Sulfur Self-Doped Activated Carbon Directly Derived from Elm Flower for High-Performance Supercapacitors [J].
Chen, Hui ;
Yu, Feng ;
Wang, Gang ;
Chen, Long ;
Dai, Bin ;
Peng, Shanglong .
ACS OMEGA, 2018, 3 (04) :4724-4732
[3]   Designed formation of hollow particle-based nitrogen-doped carbon nanofibers for high-performance supercapacitors [J].
Chen, Li-Feng ;
Lu, Yan ;
Yu, Le ;
Lou, Xiong Wen .
ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (08) :1777-1783
[4]   Carbon-based supercapacitors for efficient energy storage [J].
Chen, Xuli ;
Paul, Rajib ;
Dai, Liming .
NATIONAL SCIENCE REVIEW, 2017, 4 (03) :453-489
[5]   Pseudocapacitive Charge Storage in Thick Composite MoS2 Nanocrystal-Based Electrodes [J].
Cook, John B. ;
Kim, Hyung-Seok ;
Lin, Terri C. ;
Lai, Chun-Han ;
Dunn, Bruce ;
Tolbert, Sarah H. .
ADVANCED ENERGY MATERIALS, 2017, 7 (02)
[6]   Chemical oxidation of multiwalled carbon nanotubes [J].
Datsyuk, V. ;
Kalyva, M. ;
Papagelis, K. ;
Parthenios, J. ;
Tasis, D. ;
Siokou, A. ;
Kallitsis, I. ;
Galiotis, C. .
CARBON, 2008, 46 (06) :833-840
[7]   Sustainable materials for electrochemical capacitors [J].
Fic, Krzysztof ;
Platek, Anetta ;
Piwek, Justyna ;
Frackowiak, Elzbieta .
MATERIALS TODAY, 2018, 21 (04) :437-454
[8]   Terbium-based phosphine compound: A long-term cycling life material for high-performance supercapacitor [J].
Hong, Lvyin ;
Zhou, Qianting ;
Chen, Yongsheng ;
Li, Yafeng ;
Wei, Mingdeng .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2022, 923
[9]   Enhanced electrochemical performance and high voltage window for supercapacitors based on fabric electrodes derived from tannin-Fe3+ complexes [J].
Hu, Lei ;
Zang, Limin ;
Zuo, Wusheng ;
Liu, Qifan ;
Yang, Chao ;
Liang, Chunliu ;
Qiu, Jianhui .
SYNTHETIC METALS, 2020, 269
[10]   Characterisation of activated nanoporous carbon for supercapacitor electrode materials [J].
Janes, Alar ;
Kurig, Heisi ;
Lust, Enn .
CARBON, 2007, 45 (06) :1226-1233