Vanadium-based cathode materials for rechargeable magnesium batteries

被引：17
|
作者：
Zhang, X.
Li, D.
Ruan, Q.
Liu, L.
Wang, B.
Xiong, F. [1 ]
Huang, C. [1 ]
Chu, P. K. [1 ]
机构：
[1] City Univ Hong Kong, Dept Phys, Dept Mat Sci & Engn, Kowloon, Tat Chee Ave, Hong Kong, Peoples R China
来源：
MATERIALS TODAY ENERGY | 2023年 / 32卷
关键词：
Rechargeable magnesium battery; Vanadium oxide; Vanadate; Vanadium chalcogenide; Vanadium -based phosphate; MG INTERCALATION PROPERTIES; ELECTROCHEMICAL INSERTION; ION INTERCALATION; HIGH-CAPACITY; ELECTRODE MATERIALS; V2O5; OXIDE; STORAGE; SODIUM; KINETICS;
D O I：
10.1016/j.mtener.2022.101232
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Rechargeable magnesium batteries (RMBs) are promising candidates for large-scale energy storage due to the low cost, abundant reserve, high volumetric capacity, and low redox potential of Mg anodes. Since the high theoretical capacity and energy density originate from the rich valence states of vanadium (from +2 to +5) and distortion of V-O polyhedrons, vanadium-based cathode materials are very attractive for RMBs. This paper provides a comprehensive overview of vanadium-based cathode mate-rials for RMBs including vanadium oxides, vanadates, vanadium chalcogenides, and vanadium-based phosphates. The structure, electrochemical properties, optimization strategies, structure-performance relationship, and reaction mechanisms of various vanadium-based cathode materials are described. The challenges, prospective, and future research directions of vanadium-based electrode materials are discussed. (c) 2022 Elsevier Ltd. All rights reserved.
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页数：23
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