Unlocking the Chain-Walking Process in Gold Catalysis

被引：21

作者：

Bhoyare, Vivek W. ^{[1
]}

Tathe, Akash G. ^{[1
]}

Gandon, Vincent ^{[2
]}

Patil, Nitin T. ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res Bhopal, Dept Chem, Bhopal Bypass Rd, Bhopal 462066, India

[2] Paris Saclay Univ, Inst Chim Mol & Mat Orsay, UMR CNRS 8182, Batiment Henri Moissan,17 Ave Sci, F-91400 Orsay, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2023年 / 62卷 / 46期

关键词：

Annulation; Chain-Walking; Gold Catalysis; Migratory Insertion; beta-Hydride Elimination; ISOMERIZATION POLYMERIZATION; REMOTE; COMPLEXES; INSERTION; POLYMERS; ALKENES; FUNCTIONALIZATION; CONSTRUCTION; ELIMINATIONS; REACTIVITY;

D O I：

10.1002/anie.202312786

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The successful realization of gold-catalyzed chain-walking reactions, facilitated by ligand-enabled Au(I)/Au(III) redox catalysis, has been reported for the first time. This breakthrough has led to the development of gold-catalyzed annulation reaction of alkenes with iodoarenes by leveraging the interplay of chain-walking and pi-activation reactivity mode. The reaction mechanism has been elucidated through comprehensive experimental and computational studies.

引用

页数：6

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