Effective Cr(VI) reduction over high throughput Bi-BDC MOF photocatalyst

被引:39
作者
Gao, Ya [1 ,2 ]
Yi, Xiao-Hong [1 ,2 ]
Wang, Chong-Chen [1 ,2 ,3 ]
Wang, Fei [1 ,2 ]
Wang, Peng [1 ,2 ]
机构
[1] Beijing Univ Civil Engn & Architecture, Beijing Key Lab Funct Mat Bldg Struct & Environm R, Beijing 100044, Peoples R China
[2] Beijing Univ Civil Engn & Architecture, Coconstruct Collaborat Innovat Ctr, Beijing Energy Conservat & Sustainable Urban & Rur, Beijing 100044, Peoples R China
[3] Beijing Univ Civil Engn & Architecture, 15 Yongyuan Rd, Beijing 102616, Peoples R China
基金
中国国家自然科学基金; 北京市自然科学基金;
关键词
Bi-BDC; Photocatalysis; Cr(VI) reduction; Tartaric acid; Mechanism; METAL-ORGANIC FRAMEWORKS; PERFORMANCE;
D O I
10.1016/j.materresbull.2022.112072
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
High throughput Bi-BDC metal-organic framework (BDC = benzene-1,4-dicarboxylic acid) with uniform rod-like morphology was prepared by microwave-assisted method, which could accomplish completely photocatalytic Cr (VI) reduction within 6.0 min under low-power LED UV light with the presence of tartaric acid (TA). The Cr(VI) reduction performance of as-prepared Bi-BDC photocatalyst was slightly influenced by the environmental factors including pH and different inorganic ions. The as-obtained Bi-BDC MOF could be used for five runs' operation with constant photocatalysis performance. As well, the Cr(VI) reduction mechanism with the presence of TA over the Bi-BDC photocatalyst was clarified.
引用
收藏
页数:5
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