Zinc(II) Chelate Complexes with Redox-Active o-Indophenols: Synthesis and Structure

被引：1

作者：

Ivakhnenko, E. P. ^{[1
]}

Vitkovskaya, Yu. G. ^{[1
]}

Lysenko, K. A. ^{[2
]}

Kislitsyn, S. E. ^{[1
]}

Starikov, A. G. ^{[1
]}

Knyazev, P. A. ^{[1
]}

Tereshchenko, A. A. ^{[3
]}

Minkin, V. I. ^{[1
]}

机构：

[1] Southern Fed Univ, Inst Phys & Inorgan Chem, Rostov Na Donu 344091, Russia

[2] Moscow State Pedag Univ, Moscow 119991, Russia

[3] Southern Fed Univ, Int Res Inst Smart Mat, Rostov Na Donu 344090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 68卷 / 09期

关键词：

o-indophenol; redox-active ligand; X-ray structural analysis; electrometry; quantum-chemical calculations; METAL-COMPLEXES; TAUTOMERISM; STEREODYNAMICS; DERIVATIVES; MECHANISMS; ISOMERISM; AMIDINES; KINETICS; ANALOGS; BOND;

D O I：

10.1134/S0036023623700304

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zinc(II) complexes 2, 3, and 5 with redox-amphoteric o-indophenol ligands were prepared. The molecular structures of tetracoordinate complex 2 and hexacoordinate complex 3 were determined by single-crystal X-ray diffraction. The antioxidant properties of indophenols and their complexes were studied by cyclic voltammetry (CVA) and EPR spectroscopy. Complexation of indophenols increases the oxidation potentials by more than 0.84 V and leads to the formation of stable metal-containing radicals.

引用

页码：1159 / 1168

页数：10

共 50 条

[1] Zinc(II) Chelate Complexes with Redox-Active o-Indophenols: Synthesis and Structure
E. P. Ivakhnenko
Yu. G. Vitkovskaya
K. A. Lysenko
S. E. Kislitsyn
A. G. Starikov
P. A. Knyazev
A. A. Tereshchenko
V. I. Minkin
Russian Journal of Inorganic Chemistry, 2023, 68 : 1159 - 1168
[2] Redox-active diaminoazobenzene complexes of rhodium(III): synthesis, structure and spectroscopic characterization
Roy, Sima
Pramanik, Shuvam
Ghorui, Tapas
Dinda, Soumitra
Patra, Sarat Chandra
Pramanik, Kausikisankar
NEW JOURNAL OF CHEMISTRY, 2018, 42 (07) : 5548 - 5555
[3] Heteroligand α-Diimine-Zn(II) Complexes with O,N,O′- and O,N,S-Donor Redox-Active Schiff Bases: Synthesis, Structure and Electrochemical Properties
Smolyaninov, Ivan V. V.
Poddelsky, Andrey I. I.
Burmistrova, Daria A. A.
Voronina, Julia K. K.
Pomortseva, Nadezhda P. P.
Fokin, Vasiliy A. A.
Tselukovskaya, Ekaterina D. D.
Ananyev, Ivan V. V.
Berberova, Nadezhda T. T.
Eremenko, Igor L. L.
MOLECULES, 2022, 27 (23):
[4] Stereospecific synthesis and redox properties of ruthenium(II) carbonyl complexes bearing a redox-active 1,8-naphthyridine unit
Oyama, Dai
Hamada, Takashi
Takase, Tsugiko
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (10) : 2263 - 2268
[5] Redox-active tetrahydrosalen (salan) complexes of titanium
Quiroz-Guzman, Mauricio
Oliver, Allen G.
Loza, Andrew J.
Brown, Seth N.
DALTON TRANSACTIONS, 2011, 40 (43) : 11458 - 11468
[6] Redox-Active Metal Complexes for Anticancer Therapy
Zhang, Pingyu
Sadler, Peter J.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (12) : 1541 - 1548
[7] Thiolate-Thione Redox-Active Ligand with a Six-Membered Chelate Ring via Template Condensation and Its Pt(II) Complexes
Zuckerman, Linda A.
Vargo, Natasha P.
May, Claire, V
Crockett, Michael P.
Hyre, Ariel S.
McNeely, James
Elinburg, Jessica K.
Brown, Alexander M.
Robinson, Jerome R.
Rheingold, Arnold L.
Doerrer, Linda H.
INORGANIC CHEMISTRY, 2021, 60 (17) : 13376 - 13387
[8] Aluminum Complexes with Redox-Active Formazanate Ligand: Synthesis, Characterization, and Reduction Chemistry
Mondol, Ranajit
Otten, Edwin
INORGANIC CHEMISTRY, 2019, 58 (09) : 6344 - 6355
[9] Ytterbium Complexes with Redox-Active N,N-Chelating Ligands
Lukina, D. A.
Skatova, A. A.
Kozlova, E. A.
Fedushkin, I. L.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2023, 93 (SUPPL 3) : S782 - S787
[10] Triple-Stranded Helicates of Zinc(II) and Cadmium(II) Involving a New Redox-Active Multiring Nitrogenous Heterocyclic Ligand: Synthesis, Structure, and Electrochemical and Photophysical Properties
Kundu, Nabanita
Abtab, Sk Md Towsif
Kundu, Sanchita
Endo, Akira
Teat, Simon J.
Chaudhury, Muktimoy
INORGANIC CHEMISTRY, 2012, 51 (04) : 2652 - 2661

← 1 2 3 4 5 →