Metal-Free Electrochemical Hydroboration of Olefins

被引：4
作者：
Yuan, Qilin [1 ]
Zhang, Xiao [1 ]
Guo, Lin [1 ]
Yang, Chao [1 ]
Xia, Wujiong [1 ,2 ]
机构：
[1] Harbin Inst Technol Shenzhen, Sch Sci, State Key Lab Urban Water Resource & Environm, Shenzhen 518055, Peoples R China
[2] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2023年 / 365卷 / 11期
关键词：
Electrochemical Synthesis; Alkene Hydroboration; Organoboron Derivatives; Anodic Oxidation; ADDITION-REACTIONS; ORGANIC ELECTROSYNTHESIS; BORYL RADICALS; SECONDARY; ALKENES; LIGHT; BOND; ELECTROOXIDATION; METHODOLOGY; ELECTRICITY;
D O I：
10.1002/adsc.202300286
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Herein, we reported the electrochemical hydroboration of olefins to access the organoboron derivatives in a one-pot reaction under air and at room temperature. This reaction manifold was applied to a broad range of alkenes with 40-90% yields and good functional group tolerance without using a metal catalyst or an additional hydride source. Mechanistic studies suggested that this anodic oxidation conducted in an undivided cell allowing the production of a boron radical species, which initiates the hydroboration of olefins event by a radical addition process.
引用
收藏
页码：1788 / 1793
页数：6
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