Optimization of oil yield from isothermal pyrolysis of waste polystyrene over CuO/Kaolin

被引：1
作者：
Muhammad, Aminu Bayawa [1 ]
Abdulkarim, Awwal Mohammed [1 ]
Sokoto, Abdullahi Muhammad [1 ]
Musa, Mu'azu [2 ]
Muhammad, Misbahu Ladan [1 ]
机构：
[1] Usmanu Danfodiyo Univ, Dept Energy & Appl Chem, Sokoto, Nigeria
[2] Usmanu Danfodiyo Univ, Sokoto Energy Res Ctr, Sokoto, Nigeria
来源：
JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT | 2023年 / 25卷 / 04期
关键词：
Polystyrene; Copper(II) oxide; Kaolin; Pyrolysis; Thermochemical conversion; CATALYTIC PYROLYSIS; STYRENE MONOMER; CO-PYROLYSIS; PLASTIC WASTES; LIQUID PRODUCT; DEGRADATION; CONVERSION; BIOMASS; POLYPROPYLENE; RECOVERY;
D O I：
10.1007/s10163-023-01704-w
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Isothermal pyrolysis of waste polystyrene over CuO/kaolin was investigated and optimized for maximum oil yield using Box-Behnken response surface design. The results revealed that the reaction variables affect the yields of the gaseous, liquid and char, respectively. Optimization of the reaction variables predicted an optimal yield of 96.07% at a residence time, heating rate, and catalyst loading of 45 min, 10 degrees C/min and 30%, respectively in agreement with the validation results of 95.56 +/- 1.90%. The physicochemical properties of the oil conformed with petrodiesel properties and could be used as its substitute. The oil has a 84% dominance of benzene,1,1-(1-butenylidene)bis, and the mechanism through which it was formed has been proposed.
引用
收藏
页码：2471 / 2484
页数：14
相关论文
共 77 条
  • [1] Abd El-Aziz AS., 2014, NANOSCI NANOENG, V2, P19
  • [2] Abuelgasim F, 2015, DIYALA J ENG SCI, V8, P819
  • [3] Chemical recycling of polystyrene by pyrolysis: Potential use of the liquid product for the reproduction of polymer
    Achilias, Dimitris S.
    Kanellopoulou, Iliana
    Megalokonomos, Panagiotis
    Antonakou, Eleni
    Lappas, Angelos A.
    [J]. MACROMOLECULAR MATERIALS AND ENGINEERING, 2007, 292 (08) : 923 - 934
  • [4] Thermo-catalytic pyrolysis of polystyrene in the presence of zinc bulk catalysts
    Adnan
    Shah, Jasmin
    Jan, Muhammad Rasul
    [J]. JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (05) : 2494 - 2500
  • [5] A review on thermal and catalytic pyrolysis of plastic solid waste (PSW)
    Al-Salem, S. M.
    Antelava, A.
    Constantinou, A.
    Manos, G.
    Dutta, A.
    [J]. JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2017, 197 : 177 - 198
  • [6] Recycling and recovery routes of plastic solid waste (PSW): A review
    Al-Salem, S. M.
    Lettieri, P.
    Baeyens, J.
    [J]. WASTE MANAGEMENT, 2009, 29 (10) : 2625 - 2643
  • [7] Ali M.F., 2004, Journal of Material Cycles and Waste Management, V6, P27, DOI [DOI 10.1007/S10163-003-0102-X, 10.1007/s10163-003-0102-x]
  • [8] Thermal and catalytic pyrolysis of plastic waste
    Almeida, Debora
    Marques, Maria de Fatima
    [J]. POLIMEROS-CIENCIA E TECNOLOGIA, 2016, 26 (01): : 44 - 51
  • [9] Altohami EK., 2018, U KHARTOUM ENG J, V2, P17, DOI DOI 10.53332/KUEJ.V8I2.829
  • [10] [Anonymous], 2006, J Mater Cycles Waste Manag, DOI DOI 10.1007/S10163-006-0151-Z
12345678