Synthesis and Structure of Trisubstituted closo-Decaborane [B10H7(1-IPh)(6(7),10-NHOCCH3)]: Specifics of Interaction between the [2-B10H9NH=C(OH)CH3]- Ion and PhI(OAc)2

被引：2

作者：

Voinova, V. V. ^{[1
]}

Selivanov, N. A. ^{[1
]}

Bykov, A. Yu. ^{[1
]}

Kubasov, A. S. ^{[1
]}

Zhdanov, A. P. ^{[1
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 68卷 / 06期

关键词：

closo-decaborate anion; boroxazole; iodonium derivative; NUCLEOPHILIC-ADDITION; DERIVATIVES; ANION;

D O I：

10.1134/S003602362360017X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of trisubstituted closo-decaboranes by reacting 1,2-boroxazoles with PhI(OAc) 2 was studied. The process could be implemented in a one-pot variant proceeding from borylated iminol. The reaction products were characterized by H-1, B-11, and C-13 NMR spectroscopy. The XRD structure of the compound [B10H7(1-IPh)(6,10-NHOCCH3)] was determined.

引用

页码：678 / 683

页数：6

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