Preparation and Characterization of Modified Kaolin by a Mechanochemical Method

被引:11
作者
Liang, Xiulin [1 ]
Li, Qiang [1 ]
Fang, Ying [1 ]
机构
[1] Nanjing Tech Univ, Coll Mat Sci & Engn, Nanjing 211816, Peoples R China
关键词
kaolin; KH-570; mechanochemical method; characterization; AQUEOUS-SOLUTIONS; SOUTHEASTERN BOTSWANA; HIGH-TEMPERATURE; SULFURIC-ACID; ADSORPTION; BEHAVIOR; SURFACE; NANOPARTICLES; PERFORMANCE; REMOVAL;
D O I
10.3390/ma16083099
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A mechanochemical approach was utilized to prepare modified kaolin, and the hydrophobic modification of kaolin was realized. The study aims to investigate the changes in particle size, specific surface area, dispersion ability, and adsorption performance of kaolin. The structure of kaolin was analyzed using infrared spectroscopy, scanning electron microscopy, and X-ray diffraction, and the alterations to the kaolin microstructure were thoroughly researched and discussed. The results demonstrated that this modification method can effectively improve the dispersion and adsorption capacities of kaolin. Mechanochemical modification can increase the specific surface area of kaolin particles, reduce their particle size, and improve their agglomeration behavior. The layered structure of the kaolin was partially destroyed, the degree of order was debased, and the activity of its particles was enhanced. Furthermore, organic compounds were adsorbed on the surface of the particles. The appearance of new infrared peaks in the modified kaolin's infrared spectrum suggested that the kaolin has undergone a chemical modification process, introducing new functional groups.
引用
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页数:12
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共 45 条
  • [1] A review of potentially low-cost sorbents for heavy metals
    Bailey, SE
    Olin, TJ
    Bricka, RM
    Adrian, DD
    [J]. WATER RESEARCH, 1999, 33 (11) : 2469 - 2479
  • [2] Hallmarks of mechanochemistry: from nanoparticles to technology
    Balaz, Peter
    Achimovicova, Marcela
    Balaz, Matej
    Billik, Peter
    Cherkezova-Zheleva, Zara
    Manuel Criado, Jose
    Delogu, Francesco
    Dutkova, Erika
    Gaffet, Eric
    Jose Gotor, Francisco
    Kumar, Rakesh
    Mitov, Ivan
    Rojac, Tadej
    Senna, Mamoru
    Streletskii, Andrey
    Wieczorek-Ciurowa, Krystyna
    [J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (18) : 7571 - 7637
  • [3] Preparation of cationic surfactant-modified kaolin for enhanced adsorption of hexavalent chromium from aqueous solution
    Belachew, Neway
    Hinsene, Hirpo
    [J]. APPLIED WATER SCIENCE, 2020, 10 (01)
  • [4] Chemical activation of a kaolinite under acid and alkaline conditions
    Belver, C
    Muñoz, MAB
    Vicente, MA
    [J]. CHEMISTRY OF MATERIALS, 2002, 14 (05) : 2033 - 2043
  • [5] Removal of Cu(II) by natural and acid-activated clays: An insight of adsorption isotherm, kinetic and thermodynamics
    Bhattacharyya, Krishna G.
    Sen Gupta, Susmita
    [J]. DESALINATION, 2011, 272 (1-3) : 66 - 75
  • [6] The molecular structure of kaolinite-potassium acetate intercalation complexes: A combined experimental and molecular dynamic simulation study
    Cheng, Hongfei
    Zhang, Shuai
    Liu, Qinfu
    Li, Xiaoguang
    Frost, Ray L.
    [J]. APPLIED CLAY SCIENCE, 2015, 116 : 273 - 280
  • [7] Comparative study of the microstructure and phase evolution of FeCoCrNiAl high-entropy alloy-matrix WC nanocomposite powders prepared by mechanical alloying
    Cheng, Qianqian
    Chen, Jialin
    Yi, Gewen
    Shan, Yu
    Geng, Yushan
    Wang, Juyang
    Wang, Wenzhen
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 938
  • [8] Colina FG, 2006, SILIC IND, V71, P205
  • [9] Extensive evaluation on the effect of glass powder on the rheology, strength, and microstructure of metakaolin-based geopolymer binders
    Dadsetan, Sina
    Siad, Hocine
    Lachemi, Mohamed
    Sahmaran, Mustafa
    [J]. CONSTRUCTION AND BUILDING MATERIALS, 2021, 268
  • [10] Novel reactive amino-compound: Tris(hydroxymethyl)aminomethane covalently grafted on kaolinite
    de Faria, E. H.
    Ciuffi, K. J.
    Nassar, E. J.
    Vicente, M. A.
    Trujillano, R.
    Calefi, P. S.
    [J]. APPLIED CLAY SCIENCE, 2010, 48 (03) : 516 - 521