Application of passive sampling device for exploring the occurrence, distribution, and risk of pharmaceuticals and pesticides in surface water

Pharmaceuticals and pesticides are compounds of high concern in surface waters around the world. However, few studies have used passive sampling methods to screen and detect these compounds in natural waters. In this study, a self-developed passive sampler was employed to measure pharmaceuticals and pesticides in the rivers of Nanjing, China. A total of 41 pharmaceuticals and 11 pesticides were detected, among which antibiotic and insecticide were the predominant classes, respectively. Valproic acid, caffeine and triclosan from the pharmaceuticals, and isoprocarb and imidacloprid from the pesticides were found frequently with high concentrations. At most sampling sites, the concentration ratios of caffeine versus carbamazepine exceeded 10, and even above 50, indicating relatively poor efficiency of wastewater treatment, or possibly the direct discharge of raw sewage, or other unknown source of pollution. It was found that the concentrations and ecological risks in the northern area of Yangtze River were higher than those in the southern area of Yangtze River, implying that economic development and population density were not the main contributors to the discovered pollution. The total concentration of pharmaceuticals and pesticides in Qinhuai River increased gradually with the direction of water flow, demonstrating the success of water diversion project in flushing and scouring pollutants.