Metal-Free Oxidative Cross-Dehydrogenative Coupling of Alkenes with Thiophenols

被引：2

作者：

Li, Chunsheng ^{[1
]}

Liao, Mingjian ^{[1
]}

He, Zhiquan ^{[1
]}

Chen, Yunbing ^{[1
]}

Mai, Jingna ^{[1
]}

Dong, Rui ^{[1
]}

Chen, Junhua ^{[1
]}

Chen, Lianfen ^{[1
]}

机构：

[1] Zhaoqing Univ, Sch Environm & Chem Engn, Zhaoqing 526061, Peoples R China

来源：

CHEMISTRYSELECT | 2023年 / 8卷 / 20期

基金：

中国国家自然科学基金;

关键词：

Metal-Free; Cross-Dehydrogenative Coupling; Regioselective; Radical addition; Allylic sulfides; C-H OXYGENATION; BOND FORMATION; GRIGNARD-REAGENTS; GREEN CHEMISTRY; C(SP(3))-H; DDQ; ALLYLATION; CATALYSTS; NITROGEN; HALIDES;

D O I：

10.1002/slct.202300845

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel transition-metal-free regioselective allylic C-H thiolation of alkenes has been achieved by cross-dehydrogenative coupling strategy. The present protocol realizes efficient and highly regio- and stereo-selective functionalization of allylic C-H bonds under metal-free conditions, leading to a series of allylic thioethers in good to excellent yields. Moreover, this work features mild reaction conditions, high step- and atom-economy and good functional group tolerance.

引用

页数：5

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