Thermal and Mechanical Properties of Nano Silicon Carbide/Epoxy Composites by Surface Modification Using Oleic Acid, Imidazole, and Epoxy Silane

被引:1
作者
Sung, Kyung-Soo [1 ]
Jang, Hyerin [2 ]
Kim, Namil [2 ]
机构
[1] Protavic Korea, Res & Dev Ctr, Daejeon 34326, South Korea
[2] Hannam Univ, Dept Chem Engn, Daejeon 34054, South Korea
关键词
silicon carbide; thermal interface materials; thermal conductivity; tensile strength; die shear strength; BORON-NITRIDE; CONDUCTIVITY; BN;
D O I
10.7317/pk.2023.47.6.786
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The surface of nano-sized silicon carbide (SiC) was modified using oleic acid, imidazole, and silane coupling agents, and then the effect of surface modification on the thermal and mechanical properties of epoxy/SiC composites was investigated. At the same SiC content, the viscosity of epoxy solution was lowered noticeably by surface modifi-cation, while the adhesive strength, storage modulus, and tensile strength increased. From the thermogravimetric analysis (TGA) thermograms, the silane coupling agent was found to be stable at high temperature above 400 celcius, but oleic acid and imidazole showed the weight loss at around 200 celcius, which subsequently affecting the adhesive strength at high tem-perature. The thermal conductivity of composites containing surface-modified SiC was slightly lower than that of the untreated SiC composites.
引用
收藏
页码:786 / 792
页数:7
相关论文
共 32 条
[1]   Thermal and Electrical Properties of Surface-treated Copper Nanowire/Epoxy Composites [J].
Ahn, Kisang ;
Kim, Kiho ;
Kim, Jooheon ;
Cho, WonChul .
POLYMER-KOREA, 2015, 39 (06) :961-966
[2]   Thermal conductivity of polymer-based composites: Fundamentals and applications [J].
Chen, Hongyu ;
Ginzburg, Valeriy V. ;
Yang, Jian ;
Yang, Yunfeng ;
Liu, Wei ;
Huang, Yan ;
Du, Libo ;
Chen, Bin .
PROGRESS IN POLYMER SCIENCE, 2016, 59 :41-85
[3]   Substrate thermal conductivity effect on heat dissipation and lifetime improvement of organic light-emitting diodes [J].
Chung, Seungjun ;
Lee, Jae-Hyun ;
Jeong, Jaewook ;
Kim, Jang-Joo ;
Hong, Yongtaek .
APPLIED PHYSICS LETTERS, 2009, 94 (25)
[4]   Effect of nano-fillers on the thermal conductivity of epoxy composites with micro-Al2O3 particles [J].
Gao, Zhifang ;
Zhao, Lei .
MATERIALS & DESIGN, 2015, 66 :176-182
[5]   Thermal conductivity of 2D nano-structured boron nitride (BN) and its composites with polymers [J].
Guerra, Valentina ;
Wan, Chaoying ;
McNally, Tony .
PROGRESS IN MATERIALS SCIENCE, 2019, 100 :170-186
[6]   Preparation and characterization of surface modified boron nitride epoxy composites with enhanced thermal conductivity [J].
Hou, Jun ;
Li, Guohua ;
Yang, Na ;
Qin, Lili ;
Grami, Maryam E. ;
Zhang, Qingxin ;
Wang, Nongyue ;
Qu, Xiongwei .
RSC ADVANCES, 2014, 4 (83) :44282-44290
[7]   Novel micro-nano epoxy composites for electronic packaging application: Balance of thermal conductivity and processability [J].
Hu, Yang ;
Chen, Chao ;
Wen, Yingfeng ;
Xue, Zhigang ;
Zhou, Xingping ;
Shi, Dean ;
Hu, Guo-Hua ;
Xie, Xiaolin .
COMPOSITES SCIENCE AND TECHNOLOGY, 2021, 209
[8]   Interface thermal resistance and thermal conductivity of polymer composites at different types, shapes, and sizes of fillers: A review [J].
Jasmee, Solehah ;
Omar, Ghazali ;
Othaman, Siti Syahirah Che ;
Masripan, Nor Azmmi ;
A. Hamid, Husna .
POLYMER COMPOSITES, 2021, 42 (06) :2629-2652
[9]   Thermal Percolation Threshold and Thermal Properties of Composites with High Loading of Graphene and Boron Nitride Fillers [J].
Kargar, Fariborz ;
Barani, Zahra ;
Salgado, Ruben ;
Debnath, Bishwajit ;
Lewis, Jacob S. ;
Aytan, Ece ;
Lake, Roger K. ;
Balandin, Alexander A. .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (43) :37555-37565
[10]   Surface modification of BN/Fe3O4 hybrid particle to enhance interfacial affinity for high thermal conductive material [J].
Kim, Kiho ;
Ju, Hyun ;
Kim, Jooheon .
POLYMER, 2016, 91 :74-80