A nonpolar bond to hydrogen vs. lone pair: Incorporation of HPO32- and SeEO32- into a lead perrhenate framework

被引：6

作者：

Charkin, Dmitri O. ^{[1
]}

Grishaev, Vasili Yu. ^{[2
]}

Borisov, Artem S. ^{[2
]}

Chachin, Pavel A. ^{[1
]}

Nazarchuk, Evgeni V. ^{[2
]}

Siidra, Oleg I. ^{[2
,3
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Vorobievy Gory 1-3, Moscow 119991, Russia

[2] St Petersburg State Univ, Dept Crystallog, Inst Earth Sci, Univ Emb 7-9, St Petersburg 199034, Russia

[3] Russian Acad Sci, Kola Sci Ctr, Fersmana Str 14, Apatity 184209, Murmansk Region, Russia

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2023年 / 318卷

关键词：

Lead; Perrhenate; Selenite; Phosphite; Lone pair; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; VIBRATIONAL-SPECTRA; SELENITE; THORIUM; CHLORIDE; ANIONS;

D O I：

10.1016/j.jssc.2022.123706

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new lead perrhenate compounds, [Pb-2(ReO4)(2)(SeO3)H2O]H2O (1) and [Pb-2(ReO4)(2)(HPO3)H2O]H2O (2), were prepared by adding selenious or phosphorous acid to boiling concentrated solutions of lead perrhenate. Both compounds adopt the same crystal structure illustrating similar structural impact of lone pair and nonpolar hydrogen bond on one-sided coordination and formation of loose structural architectures. The crystal structure of 1 and 2, which corresponds to a novel structure type, consists of lead-perrhenate double layers interconnected by the selenite or phosphite anions into framework; the channels are filled by water molecules. We briefly discuss the chemistry of compounds containing both regular-shaped and 'lone-pair' or 'inert bond' anions.

引用

页数：7

共 42 条

[1]

Boldt K, 2000, EUR J INORG CHEM, P2071

[2]

Bruker A.X.S., 2014, Topas V5.0

[3] Role of Te in the low-dimensional multiferroic material FeTe2O5Br [J].

Chakraborty, Jayita ;

Ganguli, Nirmal ;

Saha-Dasgupta, Tanusri ;

Dasgupta, Indra .

PHYSICAL REVIEW B, 2013, 88 (09)

[4] Potassium rare-earth tellurite chlorides: A new branch from the old root [J].

Charkin, Dmitri O. ;

Volkov, Sergey N. ;

Dolgikh, Valeri A. ;

Aksenov, Sergey M. .

SOLID STATE SCIENCES, 2022, 129

[5] Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(II)-sulfite polymers [J].

Chilas, George I. ;

Lalioti, Nicolia ;

Vaimakis, Tiverios ;

Kubicki, Maciej ;

Kabanos, Themistoklis .

DALTON TRANSACTIONS, 2010, 39 (35) :8296-8305

[6] Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect [J].

Dai, Zhe ;

Chen, Yi-Gang ;

Guo, Yao ;

Wang, Fang ;

Yang, Yuan-Yu ;

Zhang, Xian-Ming .

INORGANIC CHEMISTRY, 2021, 60 (15) :11214-11221

[7] THE CRYSTAL STRUCTURE OF PHOSPHOROUS ACID [J].

FURBERG, S ;

LANDMARK, P .

ACTA CHEMICA SCANDINAVICA, 1957, 11 (09) :1505-1511

[8] Comprehensive derivation of bond-valence parameters for ion pairs involving oxygen [J].

Gagne, Olivier Charles ;

Hawthorne, Frank Christopher .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2015, 71 :562-578

[9]

Goerigk F.C., Z. Naturforsch. B Chem. Sci., V74

[10] CRYSTAL STRUCTURE OF CUHPO3 2H2O [J].

HANDLOVIC, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 :227-+

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