Proton-Coupled Electron Transfer in Electrocatalytic Water Splitting

被引：4
作者：
Yang, Shujiao [1 ]
Han, Jinxiu [1 ]
Zhang, Wei [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Appl Surface & Colloid Chem, Minist Educ, Xian 710119, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2023年 / 29卷 / 69期
基金：
中国国家自然科学基金;
关键词：
electrocatalysis; hydrogen evolution reaction; mechanism; oxygen evolution reaction; proton-coupled electron transfer; HYDROGEN EVOLUTION REACTION; NEUTRAL PH; ARTIFICIAL PHOTOSYNTHESIS; COPPER(II) COMPLEX; PHOTOSYSTEM-II; OXIDATION; EFFICIENT; PORPHYRINS; REACTIVITY; REDUCTION;
D O I：
10.1002/chem.202302770
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Proton-coupled electron transfer (PCET) plays a crucial role in a diverse array of natural and artificial energy conversion processes. Herein, we will introduce the fundamentals of electrochemical PCET with a focus on its role in water splitting. Besides, perspectives of future development of PCET are presented with regard to the investigation of reaction mechanisms and the design of advanced electrocatalysts. Proton-coupled electron transfer (PCET) play an important role in the conversion of energy-related small molecules. This concept introduces the fundamentals of electrochemical PCET and focuses on its role in water splitting. The further development of PCET in reaction mechanism and electrocatalyst design are also prospected.+image
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页数：10
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