Selective adsorption of polycyclic aromatic hydrocarbons by isostructural hydrogen-bonded organic frameworks

被引:6
作者
Cui, Peng [1 ,2 ,3 ]
Zhu, Qiang [2 ]
Zhang, Fangfang [1 ]
Liu, Dongni [1 ,4 ]
Zhu, Wenshuai [1 ,3 ]
机构
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
[2] Univ Liverpool, Dept Chem & Mat Innovat Factory, Liverpool L7 3NY, England
[3] China Univ Petr, Coll Chem Engn & Environm, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
[4] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China
基金
英国工程与自然科学研究理事会;
关键词
PYROMELLITIC ACID; CRYSTAL-STRUCTURE; TRIMESIC ACID;
D O I
10.1039/d3cc03131d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two isostructural hydrogen-bonded organic frameworks (HOFs) with 1-D hexagonal-shaped pores were crystallised using the molecules biphenyl-3,3 ',5,5 '-tetracarboxylic acid (BPTCA) and [1,1 ':4 ',1 '']terphenyl- 3,3 '',5,5 ''-tetracarboxylic acid (TPTCA). The desolvated HOFs, named BPTCA-2 and TPTCA-2, exhibited selective adsorption towards naphthalene and anthracene, respectively, during competitive adsorption experiments. Desolvated porous 2-D HOFs constructed with isostructural molecules exhibit selective adsorption towards naphthalene and anthracene. This is achieved by channel screening with different pore sizes.
引用
收藏
页码:12031 / 12034
页数:4
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