The recovery of gallic acid with triphenylphosphine oxide in different kind of solvents

被引：5

作者：

Aras, Sercan ^{[1
]}

Demir, Ozge ^{[1
]}

Gok, Asli ^{[1
]}

Santos, Dheiver ^{[2
]}

Kirbaslar, Sah Ismail ^{[1
]}

机构：

[1] Istanbul Univ Cerrahpasa, Engn Fac, Chem Engn Dept, TR-34320 Istanbul, Turkiye

[2] Grp Boticario Cosmet Business, Ave Rui Barbosa,4,110,Parque Fonte, Sao Jose Dos Pinhais, Parana, Brazil

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2023年 / 100卷 / 01期

关键词：

Reactive extraction; Gallic acid; Organophosphorus extractant; Triphenylphosphine oxide; N-BUTYL PHOSPHATE; REACTIVE EXTRACTION; MALONIC-ACID; SEPARATION; TEMPERATURE; DILUENT; ACETATE; AMINE; OIL;

D O I：

10.1016/j.jics.2022.100846

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, gallic acid was separated by triphenylphosphine oxide in the presence of conventional solvents. Triphenylphosphine oxide is an organophosphorus extractant and highly selective towards carboxylic acids. Reactive extraction results were compared with physical extraction results. The extraction efficiencies reached up to 61, 76, 86, 67, and 84% in the presence of triphenylphosphine oxide with oleyl alcohol, dimethyl adipate, isobutanol, methyl isopropyl ketone, and methyl ethyl ketone, respectively. Further, the number of theoretical units and the solvent to feed ratio were calculated for the practical design of a liquid-liquid extraction column. Roughly 2 to 4 theoretical units were calculated to meet the targeted extraction efficiencies. This study is the first to investigate the reactive extraction of gallic acid by triphenylphosphine oxide, and include fundamental in-formation for the recovery of gallic acid.

引用

页数：7

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