Magnesium Bismuth Ferrite Nitrogen-Doped Carbon Nanomagnetic Perovskite: Synthesis and Characterization as a High-Performance Electrode in a Supercapacitor for Energy Storage

被引:27
作者
Al-Maswari, Basheer Mohammed [3 ]
Al-Zaqri, Nabil [1 ]
Alkanad, Khaled [2 ]
AlOstoot, Fares Hezam [3 ]
Boshaala, Ahmed [4 ,5 ]
Radhika, Rayapura Thimmegowda
Venkatesha, Bellale Marigowda [3 ,6 ]
机构
[1] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[2] Univ Mysore, Dept Studies Phys, Mysuru 570006, Karnataka, India
[3] Univ Mysore, Yuvarajas Coll, Dept Chem, Mysuru 570005, Karnataka, India
[4] Univ Manchester, Res Ctr Manchester Salt & Catalysis, Manchester M15 4AN, England
[5] Libyan Author Sci Res, Tripoli, Libya
[6] Univ Mysore, Maharanis Sci Coll Women, Dept Chem, Mysuru 570005, Karnataka, India
关键词
MESOPOROUS CARBON; NANOCOMPOSITE; METAL; FILMS; OXIDE; REDUCTION; EVOLUTION; GRAPHENE; ION; MG;
D O I
10.1021/acsomega.3c00259
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bismuth ferrite (BiFeO3) is regarded as an important ABO3 perovskite in the areas of energy storage and electronics. A high-performance novel MgBiFeO3-NC nanomagnetic composite (MBFO-NC) electrode was prepared using a perovskite ABO3-inspired method as a supercapacitor for energy storage. The electrochemical behavior of the perovskite BiFeO3 has been enhanced by magnesium ion doping in the basic aquatic electrolyte as the A-site. H2-TPR revealed that the doping of Mg2+ ions at the Bi3+ sites minimizes the oxygen vacancy content and improves the electrochemical characteristics of MgBiFeO3-NC. Various techniques were used to confirm the phase, structure, surface, and magnetic properties of the MBFO-NC electrode. The prepared sample showed an enhanced mantic performance and specific area with an average nanoparticle size of similar to 15 nm. The electrochemical behavior of the three-electrode system was shown by cyclic voltammetry to have a significant specific capacity of 2079.44 F/g at 30 mV/s in 5 M KOH electrolyte. GCD analysis at a 5 A/g current density also showed an enhanced capacity improvement of 2159.88 F/g, which is 3.4x higher than that of pristine BiFeO3. At the power density of 5284.83 W/kg, the constructed MBFO-NC//MBFO-NC symmetric cell showed an exceptional energy density of 730.04 W h/kg. The MBFO-NC//MBFO-NC symmetric cell was employed as a direct practical application of the electrode material to entirely brighten the laboratory panel, which had 31 LEDs. This work proposes the utilization of duplicate cell electrodes made of MBFO-NC//MBFO-NC in portable devices for daily use.
引用
收藏
页码:16145 / 16157
页数:13
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