Novel high-efficient adsorbent based on modified gelatin/montmorillonite nanocomposite for removal of malachite green dye

被引:24
作者
Abu Elella, Mahmoud H. [1 ]
Aamer, Nema [1 ]
Abdallah, Heba M. [2 ]
Lopez-Maldonado, Eduardo A. [3 ]
Mohamed, Yasser M. A. [4 ]
El Nazer, Hossam A. [4 ]
Mohamed, Riham R. [1 ]
机构
[1] Cairo Univ, Fac Sci, Chem Dept, Giza 12613, Egypt
[2] Natl Res Ctr, Chem Ind Res Inst, Polymers & Pigments Dept, Giza 12622, Egypt
[3] Autonomous Univ Baja California, Fac Chem Sci & Engn, Tijuana 22390, Baja California, Mexico
[4] Natl Res Ctr, Photochem Dept, Giza 12622, Egypt
关键词
HEAVY-METAL IONS; AQUEOUS-SOLUTION; METHYLENE-BLUE; HYBRID NANOCOMPOSITE; MONTMORILLONITE CLAY; OXYGEN BARRIER; ACRYLIC-ACID; XANTHAN GUM; ADSORPTION; GELATIN;
D O I
10.1038/s41598-024-51321-2
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Shortage of drinking water has gained potential interest over the last few decades. Discharged industrial effluent, including various toxic pollutants, to water surfaces is one of the most serious environmental issues. The adsorption technique has become a widely studied method for the removal of toxic pollutants, specifically synthetic dyes, from wastewater due to its cost-effectiveness, high selectivity, and ease of operation. In this study, a novel gelatin-crosslinked-poly(acrylamide-co-itaconic acid)/montmorillonite (MMT) nanoclay nanocomposites-based adsorbent has been prepared for removing malachite green (MG) dye from an aqueous solution. Modified gelatin nanocomposites were synthesized using a free-radical polymerization technique in the presence and absence of MMT. Various analytical instrumentation: including FTIR, FESEM, XRD, and TEM techniques were used to elucidate the chemical structure and surface morphology of the prepared samples. Using a batch adsorption experiment, Langmuir isotherm model showed that the prepared modified gelatin nanocomposite had a maximum adsorption capacity of 950.5 mg/g using 350 mg/L of MG dye at pH 9 within 45 min. Furthermore, the regeneration study showed good recyclability for the obtained nanocomposite through four consecutive reusable cycles. Therefore, the fabricated gelatin nanocomposite is an attractive adsorbent for MG dye elimination from aqueous solutions.
引用
收藏
页数:15
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