Engineering Atomic-Scale Patterning and Resistive Switching in 2D Crystals and Application in Image Processing

The ultrathin thickness of 2D layered materials affords the control of their properties through defects, surface modification, and electrostatic fields more efficiently compared with bulk architecture. In particular, patterning design, such as moire superlattice patterns and spatially periodic dielectric structures, are demonstrated to possess the ability to precisely control the local atomic and electronic environment at large scale, thus providing extra degrees of freedom to realize tailored material properties and device functionality. Here, the scalable atomic-scale patterning in superionic cuprous telluride by using the bonding difference at nonequivalent copper sites is reported. Moreover, benefitting from the natural coupling of ordered and disordered sublattices, controllable piezoelectricity-like multilevel switching and bipolar switching with the designed crystal structure and electrical contact is realized, and their application in image enhancement is demonstrated. This work extends the known classes of patternable crystals and atomic switching devices, and ushers in a frontier for image processing with memristors. Nanopatterning design provides extra degrees of freedom to realize tailored material properties and device functionality. This research demonstrates that scalable atomic-scale patterning and controllable resistive switching can be realized in 2D superionic cuprous telluride by using the bonding difference at nonequivalent sites, and proposes a compact model for mimicking the memristor dynamics that can be used for image processing.image