Preparation and characterization of carbon quantum dots grafted Co3O4 nanocomposite for supercapacitors application

被引:19
作者
Prabakaran, Periyasami [1 ]
Arumugam, Gowdhaman [2 ]
Ramu, Perumal [1 ]
Selvaraj, Manickam [3 ]
Assiri, Mohammed A. [3 ]
Rokhum, Samuel Lalthazuala [4 ]
Periyasamy, Sivakumar [5 ]
Arjunan, Silambarasan [6 ]
Rajendran, Ramesh [2 ]
机构
[1] Govt Arts Coll Autonomous, Dept Phys, Salem 7, Tamil Nadu, India
[2] Periyar Univ, Dept Phys, Salem 636011, Tamil Nadu, India
[3] King Khalid Univ, Fac Sci, Dept Chem, Abha 61413, Saudi Arabia
[4] Natl Inst Technol, Dept Chem, Silchar 788010, Assam, India
[5] Dongguk Univ, Dept Chem, Adv Funct Nanohybrid Mat Lab, Seoul Campus, Seoul 04620, South Korea
[6] Vel Tech Rangarajan Dr Sagunthala R&D Inst Science, Dept Chem, Chennai 600062, Tamil Nadu, India
关键词
Nanomaterails; Metal oxide; Electrode materials; Supercapacitor; STATE ASYMMETRIC SUPERCAPACITORS; HIGH-PERFORMANCE; ELECTRODE MATERIALS; FACILE SYNTHESIS; NI FOAM; NANOPARTICLES; PHOTOCATALYST; NANOWIRES; COMPOSITE; NANODOTS;
D O I
10.1016/j.surfin.2023.103153
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A pure Co3O4 nanoparticles and a carbon quantum dots (CQDs) anchored cobalt oxide (Co3O4/CQD) nano-composite were synthesized by a simple hydrothermal method for supercapacitor application. The powder XRD measurement confirms the formation cubic phase of Co3O4. More HR-TEM measurements. The beneficial surface and electronic properties of CQDs were used for the refinement of the electrochemical accomplishments of Co3O4. The Co3O4/CQD and Co3O4 manifest half-cell specific capacitances of 193.8 F g-1 and 123.6 F g-1 @ current density of 4 A g-1, respectively. The introduction of CQDs into the Co3O4 matrix increased the charge-transfer process, which is primarily responsible for the improved electrochemical capabilities of the nano-composite. The hybrid asymmetric supercapacitor delivers an energy density of 2.49 W h kg-1 @ a power density of 426 W kg-2 with a capacitance retention of 81.8%.
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页数:11
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