Sustainable biochar for advanced electrochemical/energy storage applications

被引:52
|
作者
Rawat, Shivam [1 ,2 ]
Wang, Chin-Tsan [3 ,4 ]
Lay, Chyi-How [5 ]
Hotha, Srinivas [6 ]
Bhaskar, Thallada [1 ,2 ]
机构
[1] CSIR Indian Inst Petr IIP, Mat Resource Efficiency Div, Dehra Dun 248005, Uttarakhand, India
[2] Acad Sci & Innovat Res AcSIR, Sect 19, Ghaziabad 201002, Uttar Pradesh, India
[3] Natl Ilan Univ, Dept Mech & Electromech Engn, 1,Sec 1,Shennong Rd, Yilan City 260, Yilan County, Taiwan
[4] Indian Inst Technol Guwahati, Dept Chem Engn, Bongora Guwahati 781015, Assam, India
[5] Feng Chia Univ, Masters Program Green Energy Sci & Technol, 100 Wenhua Rd, Taichung 407102, Taiwan
[6] Indian Inst Sci Educ & Res, Dept Chem, Pune 411008, Maharashtra, India
关键词
Biochar; Energy storage; Battery; Supercapacitor; Hydrogen storage; POROUS CARBON; HYDROGEN STORAGE; ENERGY-STORAGE; ACTIVATED BIOCHAR; MESOPOROUS CARBON; DOPED CARBON; BIOMASS; NITROGEN; HARD; SUPERCAPACITORS;
D O I
10.1016/j.est.2023.107115
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Biochar is a carbon-rich solid prepared by the thermal treatment of biomass in an oxygen-limiting environment. It can be customized to enhance its structural and electrochemical properties by imparting porosity, increasing its surface area, enhancing graphitization, or modifying the surface functionalities by doping heteroatoms. All these features in biochar are highly desired to successfully utilize it in energy storage (in supercapacitors and batteries) or for hydrogen storage. This review focuses on the preparation strategies of biochar-based materials for energy and hydrogen storage. Also, how the structural properties of biochar can be tuned and optimized for individual applications have been discussed. The hierarchical porous structure of biochar with heteroatom surface functionalities is a desirable feature for supercapacitor application. While for battery applications, graphitic structure and interlayer spacing play a critical role. For H2 storage in biochar, a high surface area with micropore dominant structure and O-rich functional groups are required.
引用
收藏
页数:14
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