N-Heterocyclic Carbene-Pyridine Manganese Complex/Tetrabutylammonium Iodide Catalyzed Synthesis of Cyclic Carbonate from CO2 and Epoxide

被引:3
作者
Liu, Guijie [1 ]
Fu, Zhengqiang [1 ]
Chen, Fei [1 ]
Xu, Caixia [1 ]
Li, Min [1 ]
Liu, Ning [1 ]
机构
[1] Shihezi Univ, Sch Chem & Chem Engn, State Key Lab Incubat Base Green Proc Chem Engn, Shihezi 832003, Xinjiang, Peoples R China
关键词
manganese catalysis; carbon dioxide; cyclic carbonate; CO2; utilization; N-heterocyclic carbene; EFFICIENT CATALYSTS; COUPLING REACTIONS; HIGHLY EFFICIENT; SALEN COMPLEXES; DIOXIDE; FIXATION; ORGANOCATALYSTS; SYSTEM; CYCLOADDITION; VALORIZATION;
D O I
10.6023/cjoc202206047
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The bidentate N-heterocyclic carbene (NHC)-pyridine nitrogen manganese complex catalyzed coupling reaction of epoxides with CO2 was developed. The binary system resulting from the manganese complex Mn-2 in combination with tetrabutylammonium iodide (TBAI) exhibits the high activity for the synthesis of cyclic carbonate from epoxides and CO2. The binary catalytic system is suitable for a broad range of substrates scope, such as terminal epoxides and sterically hindered internal epoxides. A possible catalytic pathway was elaborated by UV-vis, FT-IR and HRMS method.
引用
收藏
页码:629 / 635
页数:7
相关论文
共 61 条
  • [31] Efficient conversion of CO2into cyclic carbonates at room temperature catalyzed by Al-salen and imidazolium hydrogen carbonate ionic liquids
    Liu, Jia
    Yang, Guoqiang
    Liu, Ying
    Zhang, Dejin
    Hu, Xingbang
    Zhang, Zhibing
    [J]. GREEN CHEMISTRY, 2020, 22 (14) : 4509 - 4515
  • [32] Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild Conditions
    Longwitz, Lars
    Steinhauer, Johannes
    Spannenberg, Anke
    Werner, Thomas
    [J]. ACS CATALYSIS, 2018, 8 (01): : 665 - 672
  • [33] Facile CO2 Cycloaddition to Epoxides by Using a Tetracarbonyl Metal Selenotungstate Derivate [{Mn(CO)3}4(Se2W11O43)]8-
    Lu, Jingkun
    Ma, Xinyi
    Singh, Vikram
    Zhang, Yujiao
    Wang, Ping
    Feng, Junwei
    Ma, Pengtao
    Niu, Jingyang
    Wang, Jingping
    [J]. INORGANIC CHEMISTRY, 2018, 57 (23) : 14632 - 14643
  • [34] CO2 Copolymers from Epoxides: Catalyst Activity, Product Selectivity, and Stereochemistry Control
    Lu, Xiao-Bing
    Ren, Wei-Min
    Wu, Guang-Peng
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2012, 45 (10) : 1721 - 1735
  • [35] Synthesis of heterobimetallic Ru-Mn complexes and the coupling reactions of epoxides with carbon dioxide catalyzed by these complexes
    Man, ML
    Lam, KC
    Sit, WN
    Ng, SM
    Zhou, ZY
    Lin, ZY
    Lau, CP
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (04) : 1004 - 1015
  • [36] Effect of an Al(III) Complex on the Regio- and Stereoisomeric Formation of Bicyclic Organic Carbonates
    Maquilon, Cristina
    Limburg, Bart
    Laserna, Victor
    Garay-Ruiz, Diego
    Gonzalez-Fabra, Joan
    Bo, Caries
    Belmonte, Marta Martinez
    Escudero-Adan, Eduardo C.
    Kleij, Arjan W.
    [J]. ORGANOMETALLICS, 2020, 39 (09) : 1642 - 1651
  • [37] Easily accessible bifunctional Zn(salpyr) catalysts for the formation of organic carbonates
    Martin, C.
    Whiteoak, C. J.
    Martin, E.
    Martinez Belmonte, M.
    Escudero-Adan, E. C.
    Kleij, A. W.
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (06) : 1615 - 1621
  • [38] Bifunctional metal-salen complexes as efficient catalysts for the fixation of CO2 with epoxides under solvent-free conditions
    Miao, Cheng-Xia
    Wang, Jin-Quan
    Wu, Ying
    Du, Ya
    He, Liang-Nian
    [J]. CHEMSUSCHEM, 2008, 1 (03) : 236 - 241
  • [39] Catalytic Conversion of Atmospheric CO2 into Organic Carbonates by Nickel(II) Complexes of Diazepane-Based N4 Ligands
    Muthuramalingam, Sethuraman
    Sankaralingam, Muniyandi
    Velusamy, Marappan
    Mayilmurugan, Ramasamy
    [J]. INORGANIC CHEMISTRY, 2019, 58 (19) : 12975 - 12985
  • [40] Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates
    Navarro, Marta
    Sanchez-Barba, Luis F.
    Garces, Andres
    Fernandez-Baeza, Juan
    Fernandez, Israel
    Lara-Sanchez, Agustin
    Rodriguez, Ana M.
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2020, 10 (10) : 3265 - 3278