N-Heterocyclic Carbene-Pyridine Manganese Complex/Tetrabutylammonium Iodide Catalyzed Synthesis of Cyclic Carbonate from CO2 and Epoxide

被引：3

作者：

Liu, Guijie ^{[1
]}

Fu, Zhengqiang ^{[1
]}

Chen, Fei ^{[1
]}

Xu, Caixia ^{[1
]}

Li, Min ^{[1
]}

Liu, Ning ^{[1
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, State Key Lab Incubat Base Green Proc Chem Engn, Shihezi 832003, Xinjiang, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 43卷 / 02期

关键词：

manganese catalysis; carbon dioxide; cyclic carbonate; CO2; utilization; N-heterocyclic carbene; EFFICIENT CATALYSTS; COUPLING REACTIONS; HIGHLY EFFICIENT; SALEN COMPLEXES; DIOXIDE; FIXATION; ORGANOCATALYSTS; SYSTEM; CYCLOADDITION; VALORIZATION;

D O I：

10.6023/cjoc202206047

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The bidentate N-heterocyclic carbene (NHC)-pyridine nitrogen manganese complex catalyzed coupling reaction of epoxides with CO2 was developed. The binary system resulting from the manganese complex Mn-2 in combination with tetrabutylammonium iodide (TBAI) exhibits the high activity for the synthesis of cyclic carbonate from epoxides and CO2. The binary catalytic system is suitable for a broad range of substrates scope, such as terminal epoxides and sterically hindered internal epoxides. A possible catalytic pathway was elaborated by UV-vis, FT-IR and HRMS method.

引用

页码：629 / 635

页数：7

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