Facile synthesize of PANI/GO/CuFe2O4 nanocomposite material with synergistic effect for superb performance supercapacitor

被引:57
作者
Ghasemi, Amirmohammad Khosravi [1 ]
Ghorbani, Mohsen [1 ]
Lashkenari, Mohammad Soleimani [2 ]
Nasiri, Noushin [3 ]
机构
[1] Babol Noshirvani Univ Technol, Dept Chem Engn, Shariati Ave, Babol 4714871167, Iran
[2] Amol Univ Special Modern Technol, Fac Engn Modern Technol, Fuel Cell Electrochem & Adv Mat Res Lab, Amol, Iran
[3] Macquarie Univ, Fac Sci & Engn, Sch Engn, Sydney, NSW 2109, Australia
关键词
Supercapacitors; Polyaniline; Asymmetric supercapacitors; COPPER FERRITE; COMPOSITE; ELECTRODE; CONSTRUCTION; FABRICATION; HYBRID;
D O I
10.1016/j.electacta.2022.141685
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Storage of energy and the pollution of the environment are two of the world's primary challenges currently. As a consequence of the diminishing supply of fossil fuels, renewable energy production has become of great sig-nificance. As a result of the high energy/power density and extended life cycle of hybrid supercapacitors, these have recently attracted the attention of energy experts. As new hybrid supercapacitor electrodes, a straightfor-ward two-step technique was developed and constructed a ternary PANI/GO/CuFe2O4 nanocomposite. The copper ferrite (CuFe2O4) nanoparticles were disseminated on graphene oxide (GO) sheets, utilizing a hydro -thermal approach, followed by an in situ polymerization procedure for a coating with polyaniline (PANI). Various electrochemical techniques were utilized to evaluate the instances' electrochemical characteristics, and the ternary system's linked topology enabled an array of electrochemical characterizations.In comparison to studies of single and binary samples, the ternary PANI/GO/CuFe2O4 electrode had the highest specific capaci-tance (SC) of 614.76 F/g at 1 A/g and the best cycle stability (remaining at 88% after 3,500 cycles) while exhibiting the lowest resistance in electrochemical impedance spectroscopy. A constructed asymmetric super -capacitor that utilized hybrid PANI/GO/CuFe2O4//GO electrodes indicated an SC of 124 F/g at 1 A/g. The asymmetric supercapacitor provided 49.72 Wh/kg and 923 W/kg energy density and specific power, respec-tively. These findings indicate that the ternary PANI/GO/CuFe2O4 composite material has the capability to be employed as unique electrode material in supercapacitor applications to produce high-efficiency and reliable energy storage devices.
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页数:11
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