Forming All-Carbon Quaternary Centers by Geminal Difunctionalization of Diazo Compounds with N,N-Disubstituted Anilines and Carbonates

被引：6
作者：
Chen, Qiang [1 ]
Huang, Tingzhong [1 ]
Shao, Ying [1 ]
Tang, Shengbiao [1 ]
Sun, Jiangtao [1 ]
机构：
[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 05期
关键词：
TERTIARY AMINE CATALYSIS; 3-COMPONENT REACTIONS; FUNCTIONALIZATION; SEQUENCE; YLIDES; BOND;
D O I：
10.1021/acs.joc.2c02730
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel three-component reaction of N,N-disubstituted anilines, diazo compounds, and allylic carbonates has been developed by using a rhodium-palladium dual catalysis, providing an effective protocol for the construction of tetrasubstituted esters bearing an all-carbon quaternary center as well as an allylic moiety in one pot.
引用
收藏
页码：3308 / 3312
页数：5
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