Synthesis, 2D-NMR analysis, DFT, and optical nonlinear studies of a new cyclic imide

被引:10
|
作者
Moker, Mustafa Hashem [1 ]
Hassan, Qusay M. A. [2 ]
Ibraheem, Heba Salman [3 ]
Sultan, H. A. [2 ]
Dhumad, Adil Muala [1 ]
Emshary, C. A. [2 ]
机构
[1] Univ Basrah, Coll Educ Pure Sci, Dept Chem, Basrah 61001, Iraq
[2] Univ Basrah, Coll Educ Pure Sci, Dept Phys, Basrah 61001, Iraq
[3] Minist Educ, Directorate Basrah Educ, Basrah 61001, Iraq
关键词
New cyclic imide; Nonlinear refractive index; Diffraction patterns; Z-scan; All-optical switching; GRAPHENE OXIDE; BISTABILITY; PATTERNS; FILMS; IV;
D O I
10.1016/j.molstruc.2023.134923
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis of (11R,15S)-13-(3-hydroxyphenyl)-9,10-dihydro-9,10-[3,4]epipy-rroloanthracene-12,14- dione, cyclic imide compound B3 , via three path ways as a new compound is detailed. The new cyclic imide compound B3 is characterized by FTIR, Mass, 1 and 2D NMR (HSQC) and UV-vis. spectra. The cyclic imide compound B3 structure is studied using B3LYP method with the 6-311G * basis set level to carry out the density functional theory (DFT) calculations. The nonlinear optical)NLO(properties of the synthesized compound are studied using low power, continuous wave (cw), visible laser beam of wavelength 473 nm via two techniques viz., diffraction patterns (DPs) and Z-scan. Nonlinear refractive index (NLRI) of the compound B3 is calculated using both techniques where as high as 7.7 x 10 -7 cm 2 /W at input power of 57 mW is obtained due to DPs technique. The all-optical switching (AOS) of the synthesized cyclic imide compound B3 is successfully examined using visible laser beams of wavelength 473 nm as controlling beam and 532 nm as the controlled beam based on the cross-passing technique. (c) 2023 Elsevier B.V. All rights reserved.
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页数:10
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