Au(III) π-Allyl Complexes: Synthesis, Structure, Reactivity, and Catalytic Applications

被引：2

作者：

Vesseur, David ^{[1
]}

Holmsen, Marte S. M. ^{[1
,2
,3
]}

Bourissou, Didier ^{[1
]}

机构：

[1] Univ Paul Sabatier, CNRS, UMR 5069, LHFA, 118 Route Narbonne, F-31062 Toulouse 09, France

[2] Univ Oslo, Ctr Mat Sci & Nanotechnol, POB 1126, N-0316 Oslo, Norway

[3] Univ Oslo, Dept Chem, POB 1033, N-0315 Oslo, Norway

来源：

CHEMCATCHEM | 2023年 / 15卷 / 20期

关键词：

pi-allyl; cyclopropyl; gold; nucleophilic addition; palladium; NUCLEOPHILIC-ATTACK; CENTRAL CARBON; LIGAND; CYCLOPROPANES; SUBSTITUTION; ACTIVATION; MECHANISM; ALCOHOLS; GOLD(I); DESIGN;

D O I：

10.1002/cctc.202300851

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

pi-Allyl complexes of transition metals are key species in organometallic chemistry and homogeneous catalysis. Palladium(II) pi-allyl complexes in particular, have gained a lot of attention, but their isoelectronic gold(III) counterparts long remained elusive. However, this situation changed during the last few years. This concept article describes the preparative routes, characterization, structure and reactivity of such species, together with their catalytic applications. The influence of the ancillary ligand at gold, either (P,C)/(N,C)-cyclometalated or (P,N)-hemilabile, is analysed in detail. The Au(III) and Pd(II) pi allyl complexes are also compared to highlight the similarities and differences.

引用

页数：9

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