Metal-Loaded Semiconductor-Photocatalysis of Alcohols for Selective Organic Synthesis: A Personal Account

被引：1

作者：

Mori, Shogo ^{[1
]}

Sakurai, Shu ^{[2
]}

Naka, Hiroshi ^{[3
,4
]}

Saito, Susumu ^{[1
,2
]}

机构：

[1] Nagoya Univ, Integrated Res Consortium Chem Sci IRCCS, Chikusa Ku, Nagoya 4648602, Japan

[2] Nagoya Univ, Grad Sch Sci, Chikusa Ku, Nagoya 4648602, Japan

[3] Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan

[4] Kyoto Univ, Ctr Promot Interdisciplinary Educ & Res, Deuterium Sci Res Unit, Sakyo Ku, Kyoto 6068501, Japan

来源：

SYNLETT | 2023年 / 34卷 / 20期

关键词：

semiconductors; photocatalysts; alcohols; dehydroxylative hydrogenolysis; dehydrogenation; N-alkylation; N-methylation; & beta; -scission; PONNDORF-VERLEY ALKYNYLATION; N-ALKYLATION; TITANIUM(IV) OXIDE; CO2; REDUCTION; WATER; AMINES; TIO2; DEHYDROGENATION; METHYLATION; ALDEHYDES;

D O I：

10.1055/a-2124-4037

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this account, we review our research over the last decade on metal-loaded semiconductor-photocatalyzed organic transforma-tions using alcohols. Different from many reactions using alcohols as mere sacrificial electron donors, our study has demonstrated alcohols as useful organic building blocks incorporated into value-added prod-ucts. Besides such recollections of previous results, we briefly introduce our ongoing project involving photocatalytic C-C bond-forming reac-tions via the C-C bond scission of tertiary alcohols.1 Introduction2 Dehydroxylative Hydrogenolysis of Allylic Alcohols3 Acceptorless Dehydrogenation of Activated/Unactivated Alcohols4 N-Alkylation of Amines using Alcohols as Alkylating Agents5 Summary and Outlook

引用

页码：2361 / 2373

页数：13

共 72 条

[1] Installing the "magic methyl" - C-H methylation in synthesis [J].

Aynetdinova, Daniya ;

Callens, Mia C. ;

Hicks, Harry B. ;

Poh, Charmaine Y. X. ;

Shennan, Benjamin D. A. ;

Boyd, Alistair M. ;

Lim, Zhong Hui ;

Leitch, Jamie A. ;

Dixon, Darren J. .

CHEMICAL SOCIETY REVIEWS, 2021, 50 (09) :5517-5563

[2] The Methylation Effect in Medicinal Chemistry [J].

Barreiro, Eliezer J. ;

Kuemmerle, Arthur E. ;

Fraga, Carlos A. M. .

CHEMICAL REVIEWS, 2011, 111 (09) :5215-5246

[3] Tuning oxygen vacancy content in TiO2 nanoparticles to enhance the photocatalytic performance [J].

Bi, Xiang ;

Du, Gaohui ;

Kalam, Abul ;

Sun, Dongfeng ;

Yu, Yuan ;

Su, Qingmei ;

Xu, Bingshe ;

Al-Sehemi, Abdullah G. .

CHEMICAL ENGINEERING SCIENCE, 2021, 234

[4] Synthesis of propylene from renewable allyl alcohol by photocatalytic transfer hydrogenolysis [J].

Caner, Joaquim ;

Liu, Zijun ;

Takada, Yuki ;

Kudo, Akihiko ;

Naka, Hiroshi ;

Saito, Susumu .

CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (11) :4093-4098

[5] Mechanistic insight into the photocatalytic N-alkylation of piperazine with alcohols over TiO2 supported Pd catalysts [J].

Chen, Weikun ;

Fu, Xiao ;

Liu, Xiaoying ;

Ye, Linmin ;

Yuan, Youzhu .

MOLECULAR CATALYSIS, 2023, 538

[6] Photocatalytic oxidation of ketones in the gas phase over TiO2 thin films:: a kinetic study on the influence of water vapor [J].

Coronado, JM ;

Zorn, ME ;

Tejedor-Tejedor, I ;

Anderson, MA .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 43 (04) :329-344

[7] Reactions in the Photocatalytic Conversion of Tertiary Alcohols on Rutile TiO2(110) [J].

Courtois, Carla ;

Eder, Moritz ;

Schnabl, Kordula ;

Walenta, Constantin A. ;

Tschurl, Martin ;

Heiz, Ulrich .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (40) :14255-14259

[8] Native Chemical Ligation Combined with Desulfurization and Deselenization: A General Strategy for Chemical Protein Synthesis [J].

Dawson, Philip E. .

ISRAEL JOURNAL OF CHEMISTRY, 2011, 51 (8-9) :862-867

[9] A Systematic Cheminformatics Analysis of Functional Groups Occurring in Natural Products [J].

Ertl, Peter ;

Schuhmann, Tim .

JOURNAL OF NATURAL PRODUCTS, 2019, 82 (05) :1258-1263

[10] Selectivity Control in Photocatalytic Transfer Hydrogenation of Bio-based Aldehydes [J].

Fu, Hongmei ;

Chen, Haijun ;

Gao, Beibei ;

Lu, Tianliang ;

Su, Yunlai ;

Zhou, Lipeng ;

Liu, Meijiang ;

Li, Hongji ;

Yang, Xiaomei .

CHEMCATCHEM, 2022, 14 (13)

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