Investigating the Mechanical, Thermal, and Crystalline Properties of Raw and Potassium Hydroxide Treated Butea Parviflora Fibers for Green Polymer Composites

被引:7
作者
Mohan, Abisha [1 ]
Priya, Retnam Krishna [1 ]
Arunachalam, Krishna Prakash [2 ]
Avudaiappan, Siva [3 ,4 ,5 ]
Maureira-Carsalade, Nelson [6 ]
Roco-Videla, Angel [7 ]
机构
[1] Manonmaniam Sundaranar Univ, Holy Cross Coll, PG & Res Dept Phys, Tirunelveli 627012, India
[2] Anna Univ, Dept Civil Engn, Univ Coll Engn Nagercoil, Nagercoil 629004, Tamil Nadu, India
[3] Univ Concepcion, Dept Ingn Civil, Concepcion 4070386, Chile
[4] Pontificia Univ Catolica Chile, Ctr Nacl Excelencia Ind Madera CENAMAD, Ave Vicuna Mackenna 4860, Santiago 8330024, Chile
[5] SIMATS, Dept Physiol, Saveetha Dent Coll & Hosp, Chennai 600077, Tamil Nadu, India
[6] Univ Catolica Santisima Concepcion, Dept Ingn Civil, Concepcion 4090541, Chile
[7] Univ Amer, Fac Salud & Ciencias Sociales, Santiago 7500975, Chile
关键词
green composites; stem fiber; crystallinity; thermal behavior; reinforcement material; NATURAL CELLULOSIC FIBER; CHEMICAL TREATMENTS; PHYSICOCHEMICAL PROPERTIES; HYBRID COMPOSITES; SURFACE-TREATMENT; EXTRACTION; TENSILE; HEMICELLULOSES; REINFORCEMENT; STRENGTH;
D O I
10.3390/polym15173522
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The only biotic factor that can satisfy the needs of human species are plants. In order to minimize plastic usage and spread an immediate require of environmental awareness, the globe urges for the development of green composite materials. Natural fibers show good renewability and sustainability and are hence utilized as reinforcements in polymer matrix composites. The present work concerns on the usage of Butea parviflora fiber (BP), a green material, for high end applications. The study throws light upon the characterization of raw and potassium hydroxide (KOH)-treated Butea Parviflora plant, where its physical, structural, morphological, mechanical, and thermal properties are analyzed using the powder XRD, FTIR spectroscopy, FESEM micrographs, tensile testing, Tg-DTA, Thermal conductivity, Chemical composition, and CHNS analysis. The density values of untreated and KOH-treated fibers are 1.238 g/cc and 1.340 g/cc, respectively. The crystallinity index of the treated fiber has significantly increased from 83.63% to 86.03%. The cellulose content of the treated fiber also experienced a substantial increase from 58.50% to 60.72%. Treated fibers exhibited a reduction in both hemicelluloses and wax content. Spectroscopic studies registered varying vibrations of functional groups residing on the fibers. SEM images distinguished specific changes on the raw and treated fiber surfaces. The Availability of elements Carbon, Nitrogen, and Hydrogen were analyzed using the CHNS studies. The tensile strength and modulus of treated fibers has risen to 192.97 MPa and 3.46 Gpa, respectively. Thermal conductivity (K) using Lee's disc showed a decrement in the K values of alkalized BP. The activation energy Ea lies between 55.95 and 73.15 kJ/mol. The fibers can withstand a good temperature of up to 240 & DEG;C, presenting that it can be tuned in for making sustainable composites.
引用
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页数:17
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