A lens-shaped supramolecule based on the bulky pentaphosphaferrocene [CpBIGFe(η5-P5)] and CuBr2

被引：0

作者：

Heinl, Sebastian ^{[1
]}

Peresypkina, Eugenia ^{[1
]}

Kremer, Werner ^{[2
]}

Scheer, Manfred ^{[1
]}

机构：

[1] Univ Regensburg, Inst Inorgan Chem, Univ Str 31, D-93040 Regensburg, Germany

[2] Univ Regensburg, Inst Biophys & Phys Biochem, Univ Str 31, D-93040 Regensburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 68期

关键词：

COORDINATION; C-60; CP-ASTERISK-FE(ETA(5)-P-5); COMPLEXES; MOLECULES; KEPLERATE; CLUSTER; LIGAND; OXIDE; UNITS;

D O I：

10.1039/d3cc03244b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Besides inherent fullerene-like hollow spheres, the metallasupramolecular chemistry of pentaphosphaferrocenes and CuBr2 afforded a conceptually new product, a compact 3.2 nm sized supramolecule [{1d}(6)(CuBr)(32)(CH3CN)(6)] formed by six largest pentaphosphaferrocene units [(CpFe)-Fe-BIG(& eta;(5)-P-5)] (1d: Cp-BIG = & eta;(5)-C-5(4-nBuC(6)H(4))(5)) so far and a framework of 32 copper and 32 bromide ions.

引用

页码：10263 / 10266

页数：4

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