Upconversion Luminescence through Cooperative and Energy-Transfer Mechanisms in Yb3+-Metal-Organic Frameworks

被引:41
|
作者
Xie, Yao [1 ,2 ]
Sun, Guotao
Mandl, Gabrielle A. A. [4 ]
Maurizio, Steven L. L. [4 ]
Chen, Jiabo [2 ]
Capobianco, John A. A. [4 ]
Sun, Lining [1 ,2 ,3 ]
机构
[1] Shanghai Univ, Coll Sci, Dept Phys, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China
[3] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China
[4] Concordia Univ, Ctr Nanosci Res, Dept Chem & Biochem, Montreal, PQ H4B 1R6, Canada
基金
加拿大自然科学与工程研究理事会; 中国国家自然科学基金;
关键词
Cooperative Luminescence; Energy Transfer; Lanthanides; Metal-Organic Frameworks; Upconversion Luminescence; METAL-ORGANIC FRAMEWORK; GROWTH; MOF;
D O I
10.1002/anie.202216269
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lanthanide-doped metal-organic frameworks (Ln-MOFs) have versatile luminescence properties, however it is challenging to achieve lanthanide-based upconversion luminescence in these materials. Here, 1,3,5-benzenetricarboxylic acid (BTC) and trivalent Yb3+ ions were used to generate crystalline Yb-BTC MOF 1D-microrods with upconversion luminescence under near infrared excitation via cooperative luminescence. Subsequently, the Yb-BTC MOFs were doped with a variety of different lanthanides to evaluate the potential for Yb3+-based upconversion and energy transfer. Yb-BTC MOFs doped with Er3+, Ho3+, Tb3+, and Eu3+ ions exhibit both the cooperative luminescence from Yb3+ and the characteristic emission bands of these ions under 980 nm irradiation. In contrast, only the 497 nm upconversion emission band from Yb3+ is observed in the MOFs doped with Tm3+, Pr3+, Sm3+, and Dy3+. The effects of different dopants on the efficiency of cooperative luminescence were established and will provide guidance for the exploitation of Ln-MOFs exhibiting upconversion.
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页数:7
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