Spectral, optical, and thermal analyses of tris-(thiourea) zinc sulfate nonlinear optical crystals

被引:3
作者
Albert, Helen Merina [1 ]
Jemima, T. [1 ]
Gonsago, C. Alosious [2 ]
机构
[1] Sathyabama Inst Sci & Technol, Dept Phys, Chennai, Tamil Nadu, India
[2] Mohamed Sathak Coll Arts & Sci, Dept Elect Sci, Chennai, Tamil Nadu, India
关键词
Crystal growth; XRD; FTIR; UV; TG/DTA; SINGLE-CRYSTALS; NLO MATERIAL; GROWTH; MONOHYDRATE;
D O I
10.1080/00150193.2023.2243560
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The current research uses a slow evaporation procedure to create Thiourea Zinc sulfate (TTZS), crystal. Powder-XRD, Fourier transforms infrared (FTIR), UV-visible, and thermal and second harmonic generation have all been used to describe the TTZS. The TTZS crystallized in an orthorhombic form, based on XRD. The functional groups and vibrational modes were validated by FTIR. The transparency over the UV-visible spectrum has been confirmed by UV spectroscopy. The SHG test illustrates the creation of second harmonic signals from samples. The thermal response of TTZS is shown by the TG/DTA. The findings suggest that TTZS might be a potential NLO material.
引用
收藏
页码:167 / 175
页数:9
相关论文
共 50 条
[31]   Investigation of optical and electrical properties of L-Cystein doped zinc thiourea chloride (ZTC) crystal for nonlinear optical (NLO) applications [J].
Anis, Mohd ;
Shaikh, R. N. ;
Shirsat, M. D. ;
Hussaini, S. S. .
OPTICS AND LASER TECHNOLOGY, 2014, 60 :124-129
[32]   Growth and characterization of tris thiourea magnesium zinc sulphate single crystals [J].
Bhuvaneswari, N. ;
Baskar, K. ;
Dhanasekaran, R. .
OPTIK, 2015, 126 (23) :3731-3736
[33]   Enhanced optical, dielectric and piezoelectric behavior in dye doped zinc tris-thiourea sulphate (ZTS) single crystals [J].
Bhandari, Sonia ;
Sinha, Nidhi ;
Ray, Geeta ;
Kumar, Binay .
CHEMICAL PHYSICS LETTERS, 2014, 591 :10-15
[34]   Growth and characterization of semi-organic nonlinear optical crystalUrea thiourea cadmium sulfate [J].
Redrothu Hanumantharao ;
S. Kalainathan .
Journal of Thermal Analysis and Calorimetry, 2013, 114 :239-243
[35]   L-citrulline (LC) doped zinc tris-thiourea sulfate (ZTS) single crystals for photonic applications [J].
Suresh Kumar, B. ;
Jagadeesh, M. R. ;
Madhu, C. ;
Suresh Kumar, H. M. .
INDIAN JOURNAL OF PHYSICS, 2022, 96 (08) :2293-2301
[36]   Spectral, optical, thermal and mechanical studies on L-Histidine oxalate crystals [J].
Dhas, S. Sahaya Jude ;
Das, S. Jerome .
ARABIAN JOURNAL OF CHEMISTRY, 2017, 10 :S854-S858
[37]   Nucleation kinetics of a new nonlinear optical crystal Urea-thiourea zinc chloride [J].
Mojumdar, S. C. ;
Madhurambal, G. ;
Mariappan, M. ;
Ravindran, B. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2011, 104 (03) :901-907
[38]   Molecular origins of nonlinear optical activity in zinc tris(thiourea)sulfate revealed by high-resolution x-ray diffraction data and ab initio calculations [J].
Cole, Jacqueline M. ;
Hickstein, Daniel D. .
PHYSICAL REVIEW B, 2013, 88 (18)
[39]   Growth and Evaluation of Linear Optical, Nonlinear Optical, Thermal, Mechanical and Magnetic Properties of Lithium Sodium Sulfate Single Crystals [J].
Punniyamoorthy, R. ;
Manimekalai, R. ;
Pasupathi, G. .
CRYSTAL RESEARCH AND TECHNOLOGY, 2018, 53 (10)
[40]   Influence of transition metal doping on tris(thiourea)zinc(II) sulphate crystals [J].
Rajasekar, M. ;
Muthu, K. ;
Meenatchi, V. ;
Mahadevan, C. K. ;
Meenakshisundaram, S. P. .
OPTIK, 2014, 125 (02) :710-713