Plant Design for the Conversion of Plastic Waste into Valuable Chemicals (Alkyl Aromatics)

被引:7
作者
Alali, Sabah A. S. [1 ]
Aldaihani, Meshal K. M. B. J. [1 ]
Alanezi, Khaled M. [1 ]
机构
[1] Publ Author Appl Educ & Training PAAET, Coll Technol Studies CTS, Chem Engn Technol Dept, Kuwait 70654, Kuwait
来源
APPLIED SCIENCES-BASEL | 2023年 / 13卷 / 16期
关键词
upcycling; pyrolysis; depolymerization; repolymerization; high-density polyethylene (HDPE); low-density polyethylene (LDPE); monomers; catalyst; alkyl aromatics; PYROLYSIS; OPTIMIZATION;
D O I
10.3390/app13169221
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The exponential increase in production and consumption of plastic has led to accumulation of plastic waste in the environment, resulting in detrimental impacts on human health and the natural environment. Plastic pollution not only stems from discarded plastics but also from the chemicals released during plastic production and decomposition. Various waste management strategies exist for plastic waste, including landfilling, recycling, conversion to liquid fuel, and upcycling. Landfilling, which is a prevalent method, contributes to long-term environmental degradation. Recycling is practiced worldwide, but its percentage remains low, particularly in regions like South Asia. Conversion to liquid fuel through pyrolysis has been explored as a viable solution, although commercialization faces challenges. Upcycling, which involves depolymerization and repolymerization, offers an avenue to recycle plastic waste into valuable chemicals, specifically focusing on high-density polyethylene (HDPE) and low-density polyethylene (LDPE). Currently, HDPE and LDPE make up 36% of all plastic trash by mass, but they have the potential to account for far more. When plastic waste is incinerated or buried in the earth, it generates carbon dioxide and heat, which pollute our environment. Depolymerization is a way to chemically recycle plastic waste into monomers, but this process requires a large amount of energy. Controlled partial depolymerization can transform PE into new, high-quality products at a temperature of more than 400 & DEG;C with or without a catalyst. In this study, we provide a novel approach for the conversion of plastic waste, particularly HDPE and LDPE, into valuable alkyl aromatics. By implementing controlled partial depolymerization, we propose a plant design capable of transforming plastic waste into high-quality chemicals. The design aims to optimize energy consumption, process efficiency, and product quality. The research findings contribute to sustainable plastic waste management and the reduction in environmental pollution caused by plastic waste.
引用
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页数:24
相关论文
共 29 条
[1]  
Abreu A., 2019, Field Actions Sci Rep J Field Actions, P62
[2]   Microplastics in the environment: A critical review of current understanding and identification of future research needs [J].
Akdogan, Zeynep ;
Guven, Basak .
ENVIRONMENTAL POLLUTION, 2019, 254
[3]   Atmospheric transport and deposition of microplastics in a remote mountain catchment [J].
Allen, Steve ;
Allen, Deonie ;
Phoenix, Vernon R. ;
Le Roux, Gael ;
Jimenez, Pilar Durantez ;
Simonneau, Anaelle ;
Binet, Stephane ;
Galop, Didier .
NATURE GEOSCIENCE, 2019, 12 (05) :339-+
[4]   Review of Modelling of Pyrolysis Processes with CFD-DEM [J].
Attanayake, Don Dasun ;
Sewerin, Fabian ;
Kulkarni, Shreyas ;
Dernbecher, Andrea ;
Dieguez-Alonso, Alba ;
van Wachem, Berend .
FLOW TURBULENCE AND COMBUSTION, 2023, 111 (02) :355-408
[5]   Quantity of plastic waste input into the ocean from China based on a material flow analysis model [J].
Bai, Mengyu ;
Li, Daoji .
ANTHROPOCENE COASTS, 2020, 3 (01) :1-5
[6]   Waste Polypropylene Plastic Recycling toward Climate Change Mitigation and Circular Economy: Energy, Environmental, and Technoeconomic Perspectives [J].
Bora, Raaj R. ;
Wang, Ralph ;
You, Fengqi .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (43) :16350-16363
[7]   Observation of the degradation of three types of plastic pellets exposed to UV irradiation in three different environments [J].
Cai, Liqi ;
Wang, Jundong ;
Peng, Jinping ;
Wu, Ziqing ;
Tan, Xiangling .
SCIENCE OF THE TOTAL ENVIRONMENT, 2018, 628-629 :740-747
[8]   Effect of pyrolysis conditions on the total contents of polycyclic aromatic hydrocarbons in biochars produced from organic residues: Assessment of their hazard potential [J].
De la Rosa, Jose M. ;
Sanchez-Martin, Agueda M. ;
Campos, Paloma ;
Miller, Ana Z. .
SCIENCE OF THE TOTAL ENVIRONMENT, 2019, 667 :578-585
[9]   Tire pyrolysis char: Processes, properties, upgrading and applications [J].
Gao, Ningbo ;
Wang, Fengchao ;
Quan, Cui ;
Santamaria, Laura ;
Lopez, Gartzen ;
Williams, Paul T. .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2022, 93
[10]   A novel investigation using thermal modeling and optimization of waste pyrolysis reactor using finite element analysis and response surface methodology [J].
Garg, Shivi ;
Nayyar, Anand ;
Buradi, Abdulrajak ;
Shadangi, Krushna Prasad ;
Sharma, Prabhakar ;
Bora, Bhaskor Jyoti ;
Jain, Akshay ;
Asif Shah, Mohd .
SCIENTIFIC REPORTS, 2023, 13 (01)