Copper-Catalyzed Synthesis of S-S Bond-Containing Silanols from SCBs and Trisulfide-1,1-dioxides

被引：9

作者：

Chen, Ying ^{[1
]}

Wang, Fei ^{[1
]}

Rao, Weidong ^{[2
]}

Shen, Shusu ^{[3
]}

Sheng, Daopeng ^{[4
,5
]}

Wang, Shun-Yi ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

[2] Nanjing Forestry Univ, Coll Chem Engn, Key Lab Biomass Based Green Fuels & Chem, Nanjing 210037, Peoples R China

[3] Suzhou Univ Sci & Technol, Sch Environm Sci & Engn, Suzhou 215009, Peoples R China

[4] Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, State Key Lab Radiat Med & Protect, Suzhou 215123, Jiangsu, Peoples R China

[5] Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher E, Suzhou 215123, Jiangsu, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 13期

基金：

中国国家自然科学基金;

关键词：

HYDROLYTIC OXIDATION; SILACYCLOBUTANES; SILICON; ORGANOSILANES; SILANEDIOLS; SILYLATION;

D O I：

10.1021/acs.joc.2c02968

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this work, an efficient methodfor the copper-catalyzed ring-openinghydrolysis of silacyclobutanes to silanols was developed. This strategyhas the advantages of friendly reaction conditions, simple operation,and good functional group compatibility. No additional additives arerequired in the reaction, and the S-S bond can also be introducedinto the organosilanol compounds in one step. Furthermore, the successat the gram scale demonstrates the great potential of the developedprotocol for practical industrial applications.

引用

页码：7953 / 7961

页数：9

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