Experimental Investigation and Thermodynamic Modelling of Ag-In-Pd Ternary System

被引：2

作者：

Pavlenko, A. S. ^{[1
]}

Ptashkina, E. A. ^{[1
]}

Zhmurko, G. P. ^{[1
]}

Kabanova, E. G. ^{[1
]}

Kareva, M. A. ^{[1
]}

Khoroshilov, A. V. ^{[2
]}

Kuznetsov, V. N. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Chem Fac, Moscow, Russia

[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2023年 / 97卷 / 01期

基金：

俄罗斯科学基金会;

关键词：

palladium alloys; phase equilibria; thermodynamic modelling;

D O I：

10.1134/S0036024423010235

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phase equilibria in Ag-In-Pd ternary system were studied using Scanning electron microscopy, Energy-dispersive X-ray spectroscopy (EDX) and X-Ray diffraction method (XRD). The solubilities of the third components in Ag-In and In-Pd binary phases were established, as well as composition ranges (from 4 to 17.5 at % Ag at 25 at % In) and crystal structure of tau ternary compound (Al3Ti). New thermodynamic assessment of Ag-In-Pd ternary system was performed, basing on the published experimental data and those obtained in the present work. Good agreement was achieved between the calculation results and the experimental data on phase equilibria and thermodynamic properties of the phases. The results of the calculation reproduce well experimental DTA/DSC data of three samples (the data were not included into the optimization). This additionally supports the correctness of the obtained thermodynamic description.

引用

页码：42 / 49

页数：8

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