Pyridinium-derived polycationic covalent organic polymers for aromatic C-H bond photocatalytic oxidation

被引：5
作者：
Ma, Shuai [1 ]
Liu, Qiunan [2 ]
Cui, Jingwang [1 ]
Rao, Caihui [1 ]
Jia, Mengze [1 ]
Yao, Xinrong [1 ]
Zhang, Jie [1 ]
机构：
[1] Beijing Inst Technol, Electrophoton Convers Mat Sch Chem & Chem Engn, MOE,Key Lab Cluster Sci, Beijing Key Lab Photoelect, Beijing 102488, Peoples R China
[2] Osaka Univ, Inst Sci & Ind Res, Dept Nanocharacterizat Nanostruct & Funct, SANKEN, Osaka 5650871, Japan
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2023年 / 634卷
基金：
中国国家自然科学基金;
关键词：
Photocatalysis; Pyridinium; C-H bond activation; Covalent organic polymers; SELECTIVE OXIDATION; AEROBIC OXIDATION; COORDINATION POLYMERS; LIGHT; ACTIVATION; NANOPARTICLES; PERFORMANCE; OXYGEN;
D O I：
10.1016/j.jcis.2022.12.047
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Using oxygen in the air as the sole oxidant to oxidize hydrocarbons into high value-added compounds is a highly promising synthesis strategy with economic advantages. However, the oxidation of hydrocarbons with molecular oxygen under mild conditions is challenging due to the large C-H bond energy in hydro-carbons. Herein, a metal-free two-dimensional covalent organic polymers (COP) functionalized by pho-toactive pyridinium units has been developed for heterogeneous photocatalytic oxidation of hydrocarbons. This is the first kind of COPs material that can achieve photocatalytic oxidation of hydro-carbons without any additives or stoichiometric oxidants except for the oxygen in the air.(c) 2022 Elsevier Inc. All rights reserved.
引用
收藏
页码：431 / 439
页数：9
相关论文
共 49 条
  • [1] Hyperbranched and viologen-functionalized polyglycerols: preparation, photo- and electrochromic performance
    Cao, Liang-cheng
    Mou, Miao
    Wang, Yuechuan
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (21) : 3412 - 3418
  • [2] Engineering Lattice Disorder on a Photocatalyst: Photochromic BiOBr Nanosheets Enhance Activation of Aromatic C-H Bonds via Water Oxidation
    Cao, Xing
    Huang, Aijian
    Liang, Chao
    Chen, Hsiao-Chien
    Han, Tong
    Lin, Rui
    Peng, Qing
    Zhuang, Zewen
    Shen, Rongan
    Chen, Hao Ming
    Yu, Yi
    Chen, Chen
    Li, Yadong
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (08) : 3386 - 3397
  • [3] A photochromic composite with enhanced carrier separation for the photocatalytic activation of benzylic C-H bonds in toluene
    Cao, Xing
    Chen, Zheng
    Lin, Rui
    Cheong, Weng-Chon
    Liu, Shoujie
    Zhang, Jian
    Peng, Qing
    Chen, Chen
    Han, Tong
    Tong, Xuanjue
    Wang, Yu
    Shen, Rongan
    Zhu, Wei
    Wang, Dingsheng
    Li, Yadong
    [J]. NATURE CATALYSIS, 2018, 1 (09): : 704 - 710
  • [4] Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration
    Capaldo, Luca
    Ravelli, Davide
    Fagnoni, Maurizio
    [J]. CHEMICAL REVIEWS, 2022, 122 (02) : 1875 - 1924
  • [5] Surface-oriented fluorinated pyridinium silicone with enhanced antibacterial activity on cotton via supercritical impregnation
    Chen, Yong
    Zhang, Qiang
    Ma, Yijia
    Han, Qiuxia
    [J]. CELLULOSE, 2018, 25 (02) : 1499 - 1511
  • [6] A polyrotaxanated covalent organic network based on viologen and cucurbit[7]uril
    Das, Gobinda
    Sharma, Sudhir Kumar
    Prakasam, Thirumurugan
    Gandara, Felipe
    Mathew, Renny
    Alkhatib, Nour
    Saleh, Na'il
    Pasricha, Renu
    Olsen, John-Carl
    Baias, Maria
    Kirmizialtin, Serdal
    Jagannathan, Ramesh
    Trabolsi, Ali
    [J]. COMMUNICATIONS CHEMISTRY, 2019, 2 (1)
  • [7] Bi2MoO6/g-C3N4 of 0D/2D heterostructure as efficient photocatalyst for selective oxidation of aromatic alkanes
    Ding, Feng
    Chen, Peng
    Liu, Fan
    Chen, Lang
    Guo, Jun-Kang
    Shen, Sheng
    Zhang, Qi
    Meng, Ling-Hu
    Au, Chak-Tong
    Yin, Shuang-Feng
    [J]. APPLIED SURFACE SCIENCE, 2019, 490 : 102 - 108
  • [8] Combining Br?nsted base and photocatalysis into conjugated microporous polymers: Visible light-induced oxidation of thiols into disulfides with oxygen
    Dong, Xiaoyun
    Hao, Huimin
    Zhang, Fulin
    Lang, Xianjun
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2022, 622 : 1045 - 1053
  • [9] Triptycene-based discontinuously-conjugated covalent organic polymer photocatalysts for visible-light-driven hydrogen evolution from water
    Elewa, Ahmed M.
    Elsayed, Mohamed Hammad
    El-Mahdy, Ahmed F. M.
    Chang, Chih-Li
    Ting, Li-Yu
    Lin, Wei-Cheng
    Lu, Chia-Yeh
    Chou, Ho-Hsiu
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 285
  • [10] Application of an electron-transfer catalyst in light-induced aerobic oxidation of alcohols
    Guo, Rui-Yun
    Sun, Li
    Pan, Xin-Yi
    Yang, Xiao-Dong
    Ma, Shuai
    Zhang, Jie
    [J]. CHEMICAL COMMUNICATIONS, 2018, 54 (89) : 12614 - 12617
12345