Mo-catalyzed Friedel-Crafts alkylation using alkenes under mild condition

被引:1
作者
Taniguchi, Nobukazu [1 ]
Kitayama, Kenji [2 ]
机构
[1] Osaka Metropolitan Univ, Dept Chem, Fac Liberal Arts Sci & Global Educ, Sakai, Osaka 5998531, Japan
[2] Daicel Corp, Mat SBU, 3-1 Ofuka Cho,Kita Ku, Osaka 5300011, Japan
关键词
Molybdenum chloride; Friedel-Crafts reaction; Hydroarylation; Alkene; Arene; INTERMOLECULAR HYDROARYLATION; ARENES; EFFICIENT; SUBSTITUTION; ETHYLENE; OLEFINS; SYSTEM;
D O I
10.1016/j.tetlet.2023.154729
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Mo-catalyzed hydroarylation of alkenes can be achieved at room temperature. The procedure can perform by using electron rich arenes, and the corresponding product is obtained regioselectively as a mixture of para- and ortho-isomers in good yield. Both aryl alkenes and aliphatic alkenes are available in the procedure. On the other hand, a reaction of allylic acetates gives the corresponding allyl arenes via leaving of acetoxy group.
引用
收藏
页数:8
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