Bio-Polyethylene Composites Based on Sugar Cane and Curaua Fiber: An Experimental Study

被引:13
作者
Barbalho, Gustavo Henrique de Almeida [1 ]
Nascimento, Jose Jefferson da Silva [2 ]
da Silva, Lucineide Balbino [3 ]
Gomez, Ricardo Soares [4 ]
de Farias, Daniel Oliveira [5 ]
Diniz, Diego David Silva [6 ]
Santos, Rosilda Sousa [7 ]
de Figueiredo, Maria Jose [8 ]
de Lima, Antonio Gilson Barbosa [9 ]
机构
[1] Fed Inst Educ Sci & Technol Rio Grande Norte, BR-58190000 Canguaretama, RN, Brazil
[2] Univ Fed Campina Grande, Dept Mat Engn, BR-58429900 Campina Grande, PB, Brazil
[3] Univ Fed Paraiba, Dept Mat Engn, BR-58051900 Joao Pessoa, PB, Brazil
[4] Univ Fed Paraiba, Dept Mech Engn, BR-58051900 Joao Pessoa, PB, Brazil
[5] Univ Fed Campina Grande, Dept Prod Engn, BR-58540000 Sume, PB, Brazil
[6] Rural Fed Univ Semiarid UFERSA, Engn Dept, BR-59780000 Caraubas, RN, Brazil
[7] Rural Fed Univ Semiarid UFERSA, Dept Nat Sci Math & Stat, BR-59625900 Mossoro, RN, Brazil
[8] Univ Fed Paraiba, Agroind Management & Technol Dept, BR-58220000 Bananeiras, PB, Brazil
[9] Univ Fed Campina Grande, Dept Mech Engn, BR-58429900 Campina Grande, PB, Brazil
关键词
biopolymer; curaua fiber; compatibility; biocomposites; morphology; HIGH-DENSITY POLYETHYLENE; MECHANICAL-PROPERTIES; LIGNOCELLULOSIC FIBERS; SISAL FIBERS; MORPHOLOGY; BLENDS; IMPACT; BIOPOLYETHYLENE; POLYPROPYLENE; COPOLYMERS;
D O I
10.3390/polym15061369
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
For the purpose of renewable materials applications, Curaua fiber treated with 5% sodium hydroxide was added to high-density biopolyethylene, using an entirely Brazilian raw material of sugarcane ethanol. Polyethylene grafted with maleic anhydride was used as a compatibilizer. With the addition of curaua fiber, the crystallinity was reduced, possibly due to interactions in the crystalline matrix. A positive thermal resistance effect was observed for the maximum degradation temperatures of the biocomposites. When curaua fiber was added (5% by weight), the morphology showed interfacial adhesion, greater energy storage and damping capacity. Although curaua fiber additions did not affect the yield strength of high-density bio polyethylene, its fracture toughness improved. With the addition of curaua fiber (5% by weight), the fracture strain was greatly reduced to about 52%, the impact strength was also reduced, suggesting a reinforcing effect. Concomitantly, the modulus and the maximum bending stress, as well as the Shore D hardness of the curaua fiber biocomposites (at 3 and 5% by weight), were improved. Two important aspects of product viability were achieved. First, there was no change in processability and, second, with the addition of small amounts of curaua fiber, there was a gain in the specific properties of the biopolymer. The resulting synergies can help ensure more sustainable and environmentally friendly manufacturing of automotive products.
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页数:19
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