Influence of TiO2, Al2O3, and Basicity on Viscosity and Structure of High Titanium-Bearing Blast Furnace Slag

被引:13
作者
Zhou, Wenbo [1 ,2 ]
Li, Tingle [1 ]
Lan, Dong [1 ]
Sun, Changyu [1 ]
Yang, Songtao [1 ]
机构
[1] Univ Sci & Technol Liaoning, Sch Mat & Met, Anshan 114051, Peoples R China
[2] Fujian Sansteel Grp Co Ltd, Sanming 365000, Peoples R China
基金
中国国家自然科学基金;
关键词
blast furnace slag; slag viscosity; slag structure; TiO2; ISOTHERMAL REDUCTION KINETICS; AMPHOTERIC BEHAVIOR; SILICATE MELTS; CO GAS; RATIO; STABILITY; CAO/SIO2; PHASE; MODEL; MGO;
D O I
10.3390/ma16072575
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The viscosity of high-titanium blast furnace slag with different TiO2 content, Al2O3 content, and basicity was measured at 1653-1773 K using the rotational cylinder method. The phase composition of the slag is measured by XRD. Phase diagram of the slags is calculated by FactSage software. Ionic network structure of the slags is analyzed by FT-IR. Results show that TiO2 depolymerizes the silicate network structure, reducing viscosity at high temperature, while increasing Al2O3 content generates a more complicated silicate, increasing viscosity. Basicity affects viscosity, with higher basicity resulting in lower viscosity above 1733 K. Perovskite significantly affects the viscosity of slag. This study provides an in-depth understanding of the relationship between the composition and viscosity of high-titanium blast furnace slag, which is very important for improving production efficiency.
引用
收藏
页数:13
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