Groundwater chemistry and entropy weighted water quality index of tsunami affected and ecologically sensitive coastal region of India

Quality groundwater is the most essential prerequisite for the better livelihood of the coastal villages and a vital resource for a safe living. Seawater interaction and coastal inundation modify hydro geochemical cycles leading to gross utility as a challenge. Poor quality water intake causes diseases and seriously affects human health. In this study, the suitability of shallow drinking water sources (10-15 m) has been studied with a focus on coastal village in south west of India (Alappad coast, Kollam, Kerala) which is a host of huge placer mineral reserve of the country. This coastal stretch has good deposition of Late Quaternary sediments of heavy mineral placers subjected to severe seawater interactions. Mineralogically, garnet and heavy minerals comprises the beaches and most coastal plains of the Alappad. A concerted geological process where moving water and waves causes erosion, leads to lowering of the earth's surface -is prominent in this fragmented land. This study critically evaluates the temporal-spatial impact of these interactions in an age of varying climatic conditions and hence for reference beyond. Water quality index analysis has been attempted using the entropy weighted water quality index (EWQI) method for a total of 45 samples (15 samples season-wise). It aims to ascertain better choices of groundwater sources for domestic uses for isolated settlers endowed with estuaries, and old coastal plains with barrier beaches. Irrigation suitability was evaluated using sodium adsorption ratio (SAR) and Na%. Observed EWQ Indices (38.2 +/- 14.5) for post-monsoon (80% samples), (66.1 +/- 77.7) for monsoon (66% samples), and (71.4 +/- 71.3) for pre-monsoon (53% samples) fall in excellent category. Post-monsoon is most favoured for a better quality groundwater as evidenced by WQI of 80% among the samples tested. Ca-HCO3 is the dominant hydrochemical type observed. The mean value of iron (0.9 +/- 1.3 mg/L) exceeded the permissible limit of 0.3 mg/L during monsoon season due to mineral-water interactions. In pre-monsoon season the parameters Na+ (95.9 +/- 200.7 mg/L), Cl- (173.4 +/- 510.2 mg/L), EC (1559.3 +/- 2510.6 mu S/cm), and TDS (492.5 +/- 629.7 mg/L) were observed in higher ranges. Significant correlation (p < 0.05) prevailed between EWQI, and parameters-conductivity (0.75), TDS (0.75), Iron (0.59), Ca2+ (0.66), and Mg2+ (0.74). Principal component analysis (PCA) on chemical parameters accounted for the total variance of 84.2% in pre-monsoon, 89.9% in monsoon and 82.9% in post-monsoon. Groundwater quality is influenced by geochemical processes, salt intrusion, and human activities like fertiliser application and domestic sewage discharge. Hierarchical cluster analysis (HCA) grouped the samples into three clusters. Cluster 3 represents poor quality water (13%) in pre-monsoon (EWQI ranged 32.2-192.7), and monsoon (EWQI ranged 171.8-309.7). Cluster 3 in post-monsoon (20%) indicating good water quality (EWQI ranged 51.4-72.6). Ultimate finding is that post-monsoon groundwater is more suitable for drinking and domestic purposes for the selected coastal area.