Intermolecular Carbophosphination of Alkynes with Phosphole Oxides via Ni-Al Bimetal-Catalyzed C-P Bond Activation

被引：4

作者：

Zhang, Feng-Ping ^{[1
]}

Wang, Rong-Hua ^{[1
]}

Li, Jiang-Fei ^{[1
]}

Chen, Hao ^{[1
]}

Babu, Madala Hari ^{[1
]}

Ye, Mengchun ^{[1
]}

机构：

[1] Nankai Univ, Coll Chem, Frontiers Sci Ctr New Organ Matter, State Key Lab Elementoorgan Chem,Haihe Lab Sustain, Tianjin 300071, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2023年 / 62卷 / 49期

基金：

中国国家自然科学基金;

关键词：

Bimetallic Catalysis; C-P Activation; Carbophosphination; Nickel; Phosphepine; PARA-QUINONE METHIDES; 3+2 CYCLOADDITION; VINYL AZIRIDINES; CONTROLLED CARBOMETALATION; CYCLOPROPYL KETONES; H ACTIVATION; SELECTIVE ALKENYLATION; DIVERGENT SYNTHESIS; OXIDATIVE ADDITION; CONCISE SYNTHESIS;

D O I：

10.1002/anie.202314701

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intermolecular carbophosphination reaction of alkynes or alkenes with unreactive C-P bonds remains an elusive challenge. Herein, we used a Ni-Al bimetallic catalyst to realize an intermolecular carbophosphination reaction of alkynes with 5-membered phosphole oxides, providing a series of 7-membered phosphepines in up to 94 % yield. The intermolecular carbophosphination reaction of alkynes or alkenes with unreactive C-P bonds remains an elusive challenge. Herein, we used a Ni-Al bimetallic catalyst to realize an intermolecular carbophosphination reaction of alkynes with 5-membered phosphole oxides, providing a series of 7-membered phosphepines in up to 94 % yield.image

引用

页数：6

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