"Improving with using" effect and mechanism analysis of electrodeposited poly(1,5-diaminoanthraquinone)/carbon cloth electrode for high-performance flexible supercapacitors

As a robust and conductive substrate, carbon cloth (CC) has been modified with various pseudocapacitive materials to boost its electrochemical performance in flexible supercapacitors. Here, poly(1,5diaminoanthraquinone) (PDAA) electrodeposited CC electrodes were developed and much higher areal specific capacitance was obtained in comparison with the functionalized CC (FCC). Most importantly, an unusual phenomenon of "improving with using" was found for the optimized one, FCC@PDAA-3, which exhibited the increased capacitance retention from 150.4% to 194.8% with increasing the number of cycles from 10,000 to 50,000. Such extraordinary cyclic life was mainly ascribed to the doping and electropolymerization of the encapsulated 1,5-diaminoanthraquinone (DAA) in the immobilized PDAA during the electrochemical cycles. These findings are expected to contribute to a deeper understanding of the pseudocapacitive materials evolution during long charging/discharging cycles, favoring the design of long-life supercapacitors for practical application.