Borylated cyclobutanes via thermal [2+2]-cycloaddition

被引：3
|
作者：
Prysiazhniuk, Kateryna [1 ]
Polishchuk, Oleksandr [1 ]
Shulha, Stanislav [1 ]
Gudzikevych, Kyrylo [1 ]
Datsenko, Oleksandr P. [1 ]
Kubyshkin, Vladimir [1 ]
Mykhailiuk, Pavel K. [1 ]
机构：
[1] Enamine Ltd, Winston Churchill St 78, UA-02094 Kiev, Ukraine
来源：
CHEMICAL SCIENCE | 2024年 / 15卷 / 09期
基金：
欧洲研究理事会; 欧盟地平线“2020”;
关键词：
2+2 CYCLOADDITION; CONSTRUCTION; UNIQUE; SALTS;
D O I：
10.1039/d3sc06600b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A one-step approach to borylated cyclobutanes from amides of carboxylic acids and vinyl boronates is elaborated. The reaction proceeds via the thermal [2 + 2]-cycloaddition of in situ-generated keteniminium salts.
引用
收藏
页码：3249 / 3254
页数：6
相关论文
共 50 条
  • [31] [2+2]-CYCLOADDITION OF A VINYL CATION
    HAMMEN, G
    HANACK, M
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (08): : 614 - 615
  • [32] [2+2]CYCLOADDITION OF NITROHETEROAROMATICS WITH YNAMINES
    REINHOUDT, DN
    KOUWENHO.CG
    TETRAHEDRON LETTERS, 1974, (29) : 2503 - 2506
  • [33] [2+2]CYCLOADDITION OF ISOCYANATES TO CARBOIMIDOPHOSPHENE
    KOLODYAZHNYI, OI
    ZHURNAL OBSHCHEI KHIMII, 1982, 52 (10): : 2361 - 2362
  • [34] [2+2]-CYCLOADDITION OF ALLENES TO ALKENES
    LUKAS, JH
    KOUWENHOVEN, AP
    BAARDMAN, F
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (10): : 709 - 710
  • [35] STEREOCHEMISTRY OF A [2+2] CYCLOADDITION OF CYCLOPENTYNE
    GILBERT, JC
    BAZE, ME
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (06) : 1885 - 1886
  • [36] Thermal metal-free [2+2] cycloaddition of acetylenedicarboxylates to polysubstituted butadienes
    Prek, Benjamin
    Pockaj, Marta
    Kantlehner, Willi
    Stanovnik, Branko
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2018, 73 (07): : 501 - 513
  • [37] Intramolecular [2+2] Cycloaddition Reactions of Alkynyl Ether Derived Ketenes. A Convenient Synthesis of Donor-Acceptor Cyclobutanes
    Tran, Vincent
    Minehan, Thomas G.
    ORGANIC LETTERS, 2011, 13 (24) : 6588 - 6591
  • [38] Synthesis of cyclobutyl-fused tetralones via photolytic [2+2] Cycloaddition
    Hsueh, Nai-Chen
    Chen, Pin-Hsien
    Chang, Meng-Yang
    TETRAHEDRON, 2023, 143
  • [39] NOVEL AND FACILE ROUTE TO (+/-)-PHYSOVENINE VIA INTRAMOLECULAR [2+2]CYCLOADDITION REACTION
    SHISHIDO, K
    AZUMA, T
    SHIBUYA, M
    TETRAHEDRON LETTERS, 1990, 31 (02) : 219 - 220
  • [40] A synthesis of the hypocholesterolemic agent 1233A via asymmetric [2+2] cycloaddition
    Dymock, BW
    Kocienski, PJ
    Pons, JM
    SYNTHESIS-STUTTGART, 1998, (11): : 1655 - 1661
12345