Bi-functionality of Coral reef-like nano-range composites fabricated as g-C3N4/ppy/PSS for efficacious electrochemical super-capacitive energy accumulation and dye depletion

被引:8
作者
Arora, Rajat [1 ,3 ]
Dhanda, Monika [1 ]
Yadav, Meena [1 ]
Malik, Rinki [1 ,4 ]
Pahuja, Priti [1 ]
Ahlawat, Simran [1 ]
Rao, Vikrant Singh [2 ]
Nehra, Satya Pal [2 ]
Lata, Suman [1 ]
机构
[1] Deenbandhu Chhotu Ram Univ Sci & Technol, Dept Chem, Murthal 131039, Haryana, India
[2] Deenbandhu Chhotu Ram Univ Sci & Technol, Ctr excellence Energy & Environm Studies, Murthal 131039, Haryana, India
[3] Panipat Inst Engn & Technol, Samalkha 132102, Haryana, India
[4] MDU, Pt Neki Ram Sharma Govt Coll, Rohtak 124001, Haryana, India
关键词
Super-capacitive energy; Rose Bengal dye removal; Ample retention; High capacitance; GRAPHITIC CARBON NITRIDE; ELECTRODE MATERIALS; POROUS CARBON; PERFORMANCE; SUPERCAPACITORS; NANOCOMPOSITE; POLYPYRROLE; CONVERSION;
D O I
10.1016/j.ssi.2023.116402
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study presents a series of Coral reef-shaped composites' recipe prepared after synthesizing g-C3N4 (G), in-situ polymerized pyrrole as polypyrrole (P) and Poly (styrene sulfonate or PSS or simply S taken in varied amounts), collectively denoted as GPS, that were further explored towards super-capacitive energy accumulation behaviour and a dye's photocatalytic gradation. After getting relevant and justifying advance characterization of the synthesized composites, super-capacitive applications of the composites were studied using the three techniques based on electrochemistry. Galvanostatic Charge Discharge validated the results as this composite (0.3 GPS) exhibited a noticeable energy density of 82.86 Wh/kg along with high power density as 224.3 W/kg at 1 A/g and specific capacitance as 1223.53 F/g at 10 mV/s using cyclic voltammetry. Excellent cyclic retention of 92.31% was observed for 0.3 GPS product over 6000 cycles. A pair of gadgets also lit for two minutes when charged for three minutes at 1.1 V using asymmetric device fabricated of 0.3 GPS.Photocatalytic activity of these composites was studied against Rose Bengal dye, with an appreciable degradation efficiency of 0.3 GPS as 89.85% and also with the efficiency 74.23% after six degradation rounds. Thus, the composite evidences about its dual properties with both the functionalities working successfully.
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页数:13
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