Efficient chemo-catalytic transformation of spent coffee grounds into lactic acid using erbium triflate

被引:4
作者
Ha, Geon-Soo [1 ]
Song, Ho Seung [1 ]
Oh, Da Hae [1 ,2 ]
Mba-Wright, Mark [3 ]
Ha, Jeong-Myeong [1 ]
Yoo, Chun-Jae [1 ]
Choi, Jae-Wook [1 ]
Kim, Chang Soo [1 ]
Jeon, Byong-Hun [4 ]
Jeong, Hanseob [5 ,8 ]
Kim, Kwang Ho [1 ,6 ,7 ,9 ]
机构
[1] Korea Inst Sci & Technol, Clean Energy Res Ctr, Seoul 02792, South Korea
[2] Korea Univ, Dept Chem & Biol Engn, Seoul 02841, South Korea
[3] Iowa State Univ, Dept Mech Engn, Ames, IA 50010 USA
[4] Hanyang Univ, Dept Earth Resources & Environm Engn, 222 Wangsimni Ro, Seoul 04763, South Korea
[5] Natl Inst Forest Sci, Forest Prod & Ind Dept, Forest Ind Mat Div, Seoul 02455, South Korea
[6] Sungkyunkwan Univ, Sch Chem Engn, Suwon 16419, South Korea
[7] Sungkyunkwan Univ, KIST SKKU Carbon Neutral Res Ctr, Suwon 16419, South Korea
[8] 57 Hoegi Ro, Seoul 02455, South Korea
[9] 5 Hwarang Ro 14-Gil, Seoul 02792, South Korea
来源
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING | 2023年 / 11卷 / 05期
关键词
Circular bioeconomy; Spent coffee grounds; Catalytic conversion; Lactic acid; Technoeconomic analysis; CONVERSION;
D O I
10.1016/j.jece.2023.110682
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Developing efficient conversion technologies for waste valorization is crucial in the context of a sustainable bioeconomy. The massive generation of spent coffee grounds (SCG) has become an environmental and social concern. Although the majority of SCG is underutilized, it exhibits the potential to be converted into value-added products. Herein, we report the effective production of lactic acid (LA), a precursor of polylactic acid, from SCG through catalytic upcycling using an erbium triflate catalyst. The reaction conditions, including time, temper-ature, and catalyst loading, were optimized to maximize the LA yield. The proposed strategy converted SCG into LA with a high yield (70 mol%) within 1 h. The morphology and chemical structure of SCG were investigated. Additionally, a techno-economic analysis (TEA) was conducted, which demonstrated that an economically viable catalytic upcycling strategy can enhance the efficiency of the waste valorization process.
引用
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页数:7
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