Waste to treasure: A superwetting fiber membrane from waste PET plastic for water-in-oil emulsion separation

被引:66
作者
Chen, Hao [1 ]
Zuo, Zhengtao [1 ]
Tian, Qiong [1 ]
Xue, Songlin [1 ]
Qiu, Fengxian [1 ]
Peng, Xiaoming [2 ]
Zhang, Tao [1 ]
机构
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
[2] East China Jiaotong Univ, Sch Civil Engn & Architecture, Nanchang 330013, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
PET plastic; Fiber membrane; Oil/water separation; Superhydrophobic; Super-oleophilic; Water-in-oil emulsion;
D O I
10.1016/j.jclepro.2023.136502
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Polyethylene terephthalate (PET) plastic membrane has attracted significant attention in chemical separation and pollution control due to its high mechanical properties and excellent chemical stability. However, designing inexpensive and efficient PET membrane materials for oil-water separation from waste PET plastics is still challenging but of great significance to environmental safety and resource protection. In this work, a super-wetting PET fiber membrane with excellent structural stability and wetting selectivity was prepared from waste PET plastic, via electrostatic spinning, in-situ deposition and surface modification. The obtained superwetting PET fiber membrane exhibits the flourishing pore structure, wettability of superhydrophobic/super-oleophilic, and corrosion resistance (weak acid, strong base). Due to its stable porous structure and wettability proper-ties, the membrane is capable of separating multi-type water-in-oil emulsion successfully, while with ideal separation flux (over 1100 L center dot m(-2)center dot h(-1)), and separation efficiency (99.0-99.9%). Additionally, after the reusability tests with the least number of 40 cycles, the membrane shows favorable separation stability and excellent reusing performance, which possesses tremendous potential for efficient and continuous separation of water-in-oil emulsions. Therefore, the simple yet effective waste-to-resource strategy for waste PET plastic can not only reduce the environmental pollution caused by microplastics, but also develop an inexpensive and efficient membrane material for industrial emulsion separation.
引用
收藏
页数:9
相关论文
共 23 条
[1]   Recycling of post-consumer plastic packaging waste in the EU: Recovery rates, material flows, and barriers [J].
Antonopoulos, Ioannis ;
Faraca, Giorgia ;
Tonini, Davide .
WASTE MANAGEMENT, 2021, 126 :694-705
[2]   Enzymatic degradation of polymers: a brief review [J].
Banerjee, A. ;
Chatterjee, K. ;
Madras, G. .
MATERIALS SCIENCE AND TECHNOLOGY, 2014, 30 (05) :567-573
[3]   Stabilization of heavy metals in piggery wastewater sludge through coagulation-hydrothermal reaction-pyrolysis process and sludge biochar for tylosin removal [J].
Cai, Limiao ;
Sun, Jie ;
Cui, Lihua ;
Jiang, Yanzi ;
Huang, Zhujian .
JOURNAL OF CLEANER PRODUCTION, 2020, 260
[4]   Laminated PET-based membranes with sweat transportation and dual thermal insulation properties [J].
Chen, Yongfang ;
Zhao, Bencheng ;
Zhang, Hanlin ;
Zhang, Tao ;
Yang, Dongya ;
Qiu, Fengxian .
CHEMICAL ENGINEERING JOURNAL, 2022, 450
[5]   Dual-responsive polyacrylonitrile-based electrospun membrane for controllable oil-water separation [J].
Dou, Yong-Le ;
Yue, Xiu ;
Lv, Chong-Jiang ;
Yasin, Akram ;
Hao, Bin ;
Su, Yuhong ;
Ma, Peng-Cheng .
JOURNAL OF HAZARDOUS MATERIALS, 2022, 438
[6]   Fate and effects of polyethylene terephthalate (PET) microplastics during anaerobic digestion of alkaline-thermal pretreated sludge [J].
Hatinoglu, M. Dilara ;
Sanin, F. Dilek .
WASTE MANAGEMENT, 2022, 153 :376-385
[7]   Evaluation of PET-derived metal organic frameworks (MOFs) for water adsorption and heat storage [J].
Makhanya, Nokubonga P. ;
Oboirien, Bilainu ;
Musyoka, Nicholas ;
Ren, Jianwei ;
Ndungu, Patrick .
JOURNAL OF POROUS MATERIALS, 2023, 30 (02) :387-401
[8]   Recycling woven plastic sack waste and PET bottle waste as fiber in recycled aggregate concrete: An experimental study [J].
Ngoc Kien Bui ;
Satomi, Tomoaki ;
Takahashi, Hiroshi .
WASTE MANAGEMENT, 2018, 78 :79-93
[9]   Structural and Optical Investigations of Radiation Damage in Transparent PET Polymer Films [J].
Prasad, Shiv Govind ;
De, Abhijit ;
De, Udayan .
INTERNATIONAL JOURNAL OF SPECTROSCOPY, 2011,
[10]   A facile, alternative and sustainable feedstock for transparent polyurethane elastomers from chemical recycling waste PET in high-efficient way [J].
Pu, Mengyuan ;
Zhou, Xing ;
Liu, Xiaohui ;
Fang, Changqing ;
Wang, Dong .
WASTE MANAGEMENT, 2023, 155 :137-145